738626-20-5

Basic information

• Product Name: (S)-N-[(2-methylphenyl)phenylmethyl]-4-methylbenzenesulfonamide
• Synonyms: (S)-N-[(2-methylphenyl)phenylmethyl]-4-methylbenzenesulfonamide
• CAS NO: 738626-20-5
• Molecular Weight: 351.469
• Mol File: 738626-20-5.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: (S)-N-[(2-methylphenyl)phenylmethyl]-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-N-[(2-methylphenyl)phenylmethyl]-4-methylbenzenesulfonamide(738626-20-5)
• EPA Substance Registry System: (S)-N-[(2-methylphenyl)phenylmethyl]-4-methylbenzenesulfonamide(738626-20-5)

Safety Data

• Hazardous Substances Data: 738626-20-5(Hazardous Substances Data)

Upstream product

• 16419-60-6 2-Methylphenylboronic acid 
• 51608-60-7 phenyl N-tosyl imine 
• 70-55-3 toluene-4-sulfonamide 
• 529-20-4 2-methylphenyl aldehyde 
• 131-58-8 2-Methylbenzophenone 
• 1002116-11-1 C₂₁H₁₉NO₂S 
• 51608-60-7 N-(benzylidene)-p-methylbenzenesulfonamide 
• 3262-89-3 triphenylboroxine 
• 343598-64-1 N-(2-methylphenyl)methylidene-4-methylbenzenesulfonamide 
• 98-80-6 phenylboronic acid 
• 7294-50-0 tri-o-tolylboroxine 
• 73845-01-9 N-[(E)-2-methylphenylmethylidene]-4-methylbenzenesulfonamide 

Relevant articles and documents

Enantioselective Rh-catalyzed addition of arylboronic acids to N-tosylarylimines

A highly enantioselective rhodium-catalyzed addition of arylboronic acids to N-tosylarylimines is described, using chiral binaphtholic phosphite and phosphoramidite ligands. The best ee values (76-99%), associated with moderate to good chemical yields, we

Chiral benzene backbone-based sulfoxide-olefin ligands for highly enantioselective Rh-catalyzed addition of arylboronic acids to: N-tosylarylimines

An efficient Rh-catalyzed addition of arylboronic acids to N-tosylarylimines has been developed with chiral benzene backbone-based sulfoxide-olefin ligands, where 2-methoxy-1-naphthyl sulfinyl functionalized olefin ligands have shown to be more effective.

Asymmetric Stepwise Reductive Amination of Sulfonamides, Sulfamates, and a Phosphinamide by Nickel Catalysis

Asymmetric reductive amination of poorly nucleophilic sulfonamides was realized in the presence of nickel catalysts and titanium alkoxide. A wide range of ketones, including enolizable ketones and some biaryl ones, were converted into sulfonamides in excellent enantiomeric excess. The cyclization of sulfamates and intermolecular reductive amination of a diarylphosphinamide were also successful. Formic acid was used as a safe and economic surrogate of high-pressure hydrogen gas.