74260-40-5

Basic information

• Product Name: Stannane, tributyl[(4-methoxyphenyl)methyl]-
• CAS NO: 74260-40-5
• Molecular Formula: C20H36OSn
• Molecular Weight: 411.215
• Mol File: 74260-40-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Stannane, tributyl[(4-methoxyphenyl)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, tributyl[(4-methoxyphenyl)methyl]-(74260-40-5)
• EPA Substance Registry System: Stannane, tributyl[(4-methoxyphenyl)methyl]-(74260-40-5)

Safety Data

• Hazardous Substances Data: 74260-40-5(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 19350-72-2 N'-(4-methoxybenzylidene)-4-methylbenzenesulfonohydrazide 
• 688-73-3 tri-n-butyl-tin hydride 
• 813-19-4 bis(tri-n-butyltin) 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 499792-14-2 5-(4-methoxybenzyl)-2-nitrobenzaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 824-94-2 p-methoxybenzyl chloride 
• 105-13-5 4-Methoxybenzyl alcohol 
• 100-09-4 4-methoxybenzoic acid 
• 1657-55-2 1,2-bis(4-methoxyphenyl)ethane 
• 5406-18-8 3-(p-methoxyphenyl)-1-propanol 
• 58680-51-6 1-methoxy-4-(tosylmethyl)benzene 

Relevant articles and documents

Preparation method of alkyl tin compound or benzyl tin compound

The invention discloses a preparation method of an alkyl tin compound or a benzyl tin compound. N-tosylhydrazones, tri-n-butyltin hydride and alkali react in an organic solvent to obtain the alkyl tin compound or the benzyl tin compound. The addition of a phase transfer catalyst can effectively promote the reaction. According to the method disclosed by the invention, it is first time that the alkyl tin compound or the benzyl tin compound is directly obtained under the mild condition from N-tosylhydrazones without transition metal, the reaction efficiency is high, the reaction cost is low, and the method has good tolerance and universality on functional groups and can be widely used for preparing the alkyl tin compound or the benzyl tin compound.

SYNTHESIS OF ORGANOTRIALKYLSTANNANES. THE REACTION BETWEEN ORGANIC HALIDES AND HEXAALKYLDISTANNANES IN THE PRESENCE OF PALLADIUM COMPLEXES

The aryl halides YC6H4X (X=Br or I) have been shown to react with the distannanes (R3Sn)2 (R=n-Bu or Me) in toluene in the presence of or to give the compounds YC6H4SnR3 for (a) R=n-Bu, Y=H, p-OMe, o-Me, p-Me, m-Cl, p-Cl, m-CN, p-COCH3 and m-NO2, and (b) R=Me, Y=H, p-OMe, p-Me, p-CN, p-COCH3, m-NO2 and p-NO2.Benzyl halides YC6H4CH2X (X=Cl or Br) similarly give YC6H4CH2SnR3 for (a) R=n-Bu, Y=H, m-OMe, p-OMe, m-Cl, m-CN, and m-NO2, and (b) R=Me, Y=m-Cl, m-CN, p-CN and m-NO2.These reactions are of special value as preparative procedures in cases in which Grignard or organolithium reagents cannot be used.Allyl chloride and bromide were likewise shown to react with (n-Bu3Sn)2 to give CH2=CHCH2SnBu3, but n-BuCl and n-BuBr gave only a trace of n-Bu4Sn.The mixed dimetallo species n-Bu3SnSiMe3 was shown to react with aryl bromides YC6H4Br (X=H, p-OMe, p-Me, or p-Cl) to give the arylsilicon compounds YC6H4SiMe3, with no aryltin products.