74395-08-7Relevant articles and documents
The synthesis method of one-carbon ring expansion of cycloketone dericatives from β-selenyl cycloketone dericatives
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Paragraph 0041; 0044-0048; 0104-0108, (2020/09/08)
The present invention relates to a method for preparing a cyclic ketone derivative with an increased carbon number by performing a ring expansion reaction of a β-selenyl cyclic ketone derivative. The present invention was first developed by performing the
1,4-Addition of aryl boronic acids to α,β-unsaturated ketones catalyzed by a CCC-NHC pincer rhodium complex
Reilly, Sean W.,Box, Hannah K.,Kuchenbeiser, Glenn R.,Rubio, Ramel J.,Letko, Christopher S.,Cousineau, Kandarpa D.,Hollis, T. Keith
supporting information, p. 6738 - 6742 (2014/12/11)
An air- and water-stable CCC-NHC pincer Rh complex catalyzed the 1,4-addition of aryl boronic acids to α,β-unsaturated ketones and aldehydes. This bench top method proceeds in eco-friendly solvents including methanol and water. The scope of boronic acids was expanded to include heterocyclic examples.
Rhodium-catalyzed conjugate addition of arylindium reagents to α,β-unsaturated carbonyl compounds
Tato, Rubén,Riveiros, Ricardo,Pérez Sestelo, José,Sarandeses, Luis A.
experimental part, p. 1606 - 1611 (2012/03/11)
A novel rhodium-catalyzed conjugate addition of indium reagents to electron deficient olefins is reported. The reaction takes place in THF/MeOH at 110 °C using arylindium dichlorides, a rhodium(I)-binap complex as catalyst, and α,β-unsaturated ketones and
