745813-62-1

Basic information

• Product Name: (-)-(2S,3S)-3-methyl-2-phenyl-4-penten-2-ol
• Synonyms: (-)-(2S,3S)-3-methyl-2-phenyl-4-penten-2-ol
• CAS NO: 745813-62-1
• Molecular Weight: 176.258
• Mol File: 745813-62-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (-)-(2S,3S)-3-methyl-2-phenyl-4-penten-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(2S,3S)-3-methyl-2-phenyl-4-penten-2-ol(745813-62-1)
• EPA Substance Registry System: (-)-(2S,3S)-3-methyl-2-phenyl-4-penten-2-ol(745813-62-1)

Safety Data

• Hazardous Substances Data: 745813-62-1(Hazardous Substances Data)

Upstream product

• 69611-01-4 (Z)-2-(but-2-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 98-86-2 acetophenone 
• 136880-74-5 (E)-but-2-enyldiisopropoxyborane 
• 69611-02-5 (E)-2-(but-2-enyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Downstream Products

• 745813-71-2 (2S,3S)-toluenesulfonic acid 3-hydroxy-2-methyl-3-phenylbutyl ester 
• 14366-96-2 threo-3-Phenyl-2-methyl-butan-1,3-diol 

Relevant articles and documents

Dramatic ligand effect in catalytic asymmetric reductive aldol reaction of allenic esters to ketones

A general catalytic asymmetric reductive aldol reaction of allenic esters to ketones is described. Two distinct constitutional isomers were selectively produced depending on the reaction conditions. A combination of CuOAc/(R)-DTBM-SEGPHOS/PCy3

The mechanism and an improved asymmetric allylboration of ketones catalyzed by chiral biphenols

Giving it a boost: A mechanistic study of the enantioselective asymmetric titled reaction with allyldiisopropoxyborane catalyzed by chiral biphenols revealed a key ligand exchange process which liberates isopropyl alcohol. The addition of iPrOH to the rea

Catalytic enantioselective allylboration of ketones

The first example of catalytic enantioselective allylboration and crotylboration of simple ketones is described. High enantioselectivity (up to 93% ee) was obtained using 3 mol % CuF-iPr-DuPHOS as a chiral catalyst and 4.5 mol % La(Oi/sup