75356-81-9

Basic information

• Product Name: Lithium, (1-phenylpropyl)-
• CAS NO: 75356-81-9
• Molecular Formula: C9H11Li
• Molecular Weight: 126.127
• Mol File: 75356-81-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Lithium, (1-phenylpropyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, (1-phenylpropyl)-(75356-81-9)
• EPA Substance Registry System: Lithium, (1-phenylpropyl)-(75356-81-9)

Safety Data

• Hazardous Substances Data: 75356-81-9(Hazardous Substances Data)

Upstream product

• 93-54-9 1-Phenyl-1-propanol 
• 103-65-1 phenylpropane 
• 766-04-1 benzyllithium 

Downstream Products

• 103-65-1 phenylpropane 
• 766-04-1 benzyllithium 

Relevant articles and documents

ZUR BILDUNGSWEISE VON 1-PHENYLPROPYLLITHIUM AUS BENZYLLITHIUM UND ETHYLEN IN TETRAHYDROFURAN

3-Phenylpropyllithium primarily formed by the addition of benzyllithium to ethylene in THF does not undergo an intramolecular 1,3-proton shift to 1-phenylpropyllithium.Fast protonation by the solvent takes place instead, yielding n-propylbenzene and new ethylene.An equilibrium is then established between n-propylbenzene and additional benzyllithium, with the formation of toluene and 1-phenylpropyllithium; the equilibrium, however, strongly favours the starting materials (K293=1.1*10-4).As, on the other hand, 1-phenylpropyllithium reacts with ethylene much more rapidly than does benzyllithium, it is removed from the equilibrium and mainly branched secondary products are still obtained.