75478-73-8

Basic information

• Product Name: (methyl-3' butanal-1'-yl-3')-2 phenyl-2 dithianne-1,3
• CAS NO: 75478-73-8
• Molecular Weight: 280.455
• Mol File: 75478-73-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (methyl-3' butanal-1'-yl-3')-2 phenyl-2 dithianne-1,3(CAS DataBase Reference)
• NIST Chemistry Reference: (methyl-3' butanal-1'-yl-3')-2 phenyl-2 dithianne-1,3(75478-73-8)
• EPA Substance Registry System: (methyl-3' butanal-1'-yl-3')-2 phenyl-2 dithianne-1,3(75478-73-8)

Safety Data

• Hazardous Substances Data: 75478-73-8(Hazardous Substances Data)

Upstream product

• 5425-44-5 2-Phenyl-[1,3]dithiane 
• 107-86-8 3,3-dimethyl acrylaldehyde 

Relevant articles and documents

ADDITION CONJUGUEE DE DERIVES LITHIES DE DITHIANE-1,3 AUX ALDEHYDES αβ ETHYLENIQUES

In order to synthesize γ carbonyl aldehydes which are interesting precursors in organic synthesis, we examine the action of masked acylanions, the lithiated derivatives from 1,3-dithiane 1a and 2-phenyl-1,3-dithiane on selected unsaturated aldehydes: crotonaldehyde 2, cinnamaldehyde 3, 3-methyl butenal 4 and methacrolein 5.In THF 1a leads with the four aldehydes to allylic alcohols.However 1b gives products resulting from C=C and C=O additions.Using THF-HMPA, we show that C=C addition is generally enhanced.Furthermore, in all cases examined C=C and C=O addition take place under kinetic controll: the regioselectivity observed can be interpreted by repulsive interactions due to the substrate and the reagent structure as well as lithium-carbonyl compound interactions.