75519-88-9

Basic information

• Product Name: methyl (Z)-2-acetyl-3-benzoylacrylate
• Synonyms: methyl (Z)-2-acetyl-3-benzoylacrylate
• CAS NO: 75519-88-9
• Molecular Weight: 232.236
• Mol File: 75519-88-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: methyl (Z)-2-acetyl-3-benzoylacrylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-2-acetyl-3-benzoylacrylate(75519-88-9)
• EPA Substance Registry System: methyl (Z)-2-acetyl-3-benzoylacrylate(75519-88-9)

Safety Data

• Hazardous Substances Data: 75519-88-9(Hazardous Substances Data)

Upstream product

• 75519-85-6 5-methoxycarbonyl-4-methyl-1-phenyl-2,3,7-trioxabicyclo<2.2.1>hept-5-ene 
• 75519-87-8 methyl (E)-2-acetyl-3-benzoylacrylate 
• 59624-45-2 3-acetyl-2-methoxy-5-phenylfuran 
• 1129-37-9 4-nitrobenzaldehyde oxime 
• 75519-85-6 endo-(methyl 2,5-epidioxy-2,5-dihydro-2-methyl-5-phenylfuran-3-carboxylate) 

Relevant articles and documents

Trapping reactions of 1-methoxyfuran endo-peroxides with 4-nitrobenzaldehyde oxime. Regio- and stereoselective synthesis of the first oxime O- ethers

The synthesis of the title compounds by dye-sensitized photooxygenation of 2-methoxyfurans in the presence of 4-nitrobenzaldehyde oxime is described. The crystal structure determination of a derivative is also reported.

Photosensitized Oxidation of Furans. Part 13. Trapping Reactions of the Carbonyl Oxides Obtained from Some 2-Methoxy-5-phenylfurans

The dye-sensitized photo-oxygenation in methanol of the 2-methoxy-5-phenylfurans (1a-c), unsubstituted at C-4 with electron-withdrawing groups, leads to the hemiperacetals (4a-c).The reaction provides the first incontrovertible evidence for carbonyl oxide

Photosensitized Oxidation of Furans. III. Comparison Between Photochemically and Thermally Generated Singlet Oxygen Oxidation of 3-Methoxycarbonyl-2-methyl-5-phenylfuran

Thermal conversion of furan endo-peroxide I, obtained by photosensitized oxidation of furan II, yields very similar results to those of the oxidation of the furan II by thermally generated singlet oxygen, showing that also in the latter case the endo-peroxide I is the key intermediate.A mechanistic interpretation of the furan II-singlet oxygen reaction is reported.