756-13-8Relevant articles and documents
Method for synthesizing perfluoro(2-methyl-3-pentanone)
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Paragraph 0015; 0032-0075, (2020/04/22)
The invention discloses a method for synthesizing perfluoro(2-methyl-3-pentanone). The method comprises the following steps: in the presence of a polar aprotic solvent, carrying out an isomerization synthesis reaction in a micro-channel reactor by taking perfluoro-2,3-epoxy-2-methylpentane as a raw material and using an organic amine or metal fluoride as a catalyst to obtain a reaction product, and sequentially carrying out standing separation and rectification treatment on the reaction product to obtain perfluoro(2-methyl-3-pentanone). According to the invention, a reaction is performed by using a micro-channel reactor, so that the whole isomerization synthesis reaction cannot contact water or water vapor so as to avoid the generation of by-products and improve the conversion rate and theyield of the perfluoro(2-methyl-3-pentanone); and raw materials and a catalyst are subjected to high-speed uniform mixing and heat and mass transfer in the micro-channel reactor, so that the rate ofthe synthesis reaction is increased, the continuous and efficient synthesis of perfluoro(2-methyl-3-pentanone) is realized, and the method is good in repeatability, rapid in system response, easy forautomatic control and amplified production, almost free of amplification effect, high in safety, less in three wastes and easy for industrial production.
Method for preparing pentafluoride ethyl perfluoro isopropyl ketone through gas phases
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Paragraph 0055-0056, (2018/08/03)
The invention discloses a method for preparing pentafluoride ethyl perfluoro isopropyl ketone through gas phases. The method is characterized in that under the existence of addition catalysts, hexafluoropropylene and hexafluoropropylene oxide or pentafluoropropionyl fluoride take gas phase addition reaction to obtain the pentafluoride ethyl perfluoro isopropyl ketone, or tetrafluoroethylene and heptafluorobutyl fluoride take gas phase addition reaction to obtain the pentafluoride ethyl perfluoro isopropyl ketone. The method has the advantages that the reaction route is short; in addition, rawmaterials such as the hexafluoropropylene, the tetrafluoroethylene, the hexafluoropropylene oxide and carbonyl fluoride can be easily obtained; the cost is low; the yield of the pentafluoride ethyl perfluoro isopropyl ketone is high; the continuous large-scale industrial production can be realized through the route.
Preparation method of C6-fluoroketone
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Paragraph 0013; 0033; 0034, (2016/11/07)
The invention discloses a preparation method of C6-fluoroketone. C6-fluoroketone is called perfluoro-2-methyl-3-pentanone. The method includes the steps that in the presence of an organic guanidine catalyst and a solvent, perfluoro-2,3-epoxy-2-methylpentane reacts for 1-5 hours at the temperature of 0-80 DEG C; the organic guanidine catalyst is selected from one of or a mixture of two or more of metformin, bicyclic guanidine, chlorination bicyclic guanidine, tetramethyl guanidine and conjugated tetramethyl guanidine and other guanidyl compounds. The mole yield of the product obtained through the method is larger than 95%, reaction selectivity is high, reaction conditions are mild, and the preparation method is environmentally friendly.