75730-02-8Relevant articles and documents
Cu-Catalyzed Carbonylative Silylation of Alkyl Halides: Efficient Access to Acylsilanes
Cheng, Li-Jie,Mankad, Neal P.
, p. 80 - 84 (2020)
A Cu-catalyzed carbonylative silylation of unactivated alkyl halides has been developed, enabling efficient synthesis of alkyl-substituted acylsilanes in high yield. A variety of functional groups are tolerated under the mild reaction conditions, and prim
THE PREPARATION OF α-HYDROXYORGANOSILANES FROM α-BORYLORGANOSILANE INTERMEDIATES
Larson, Gerald L.,Argueelles, Rafael,Rosario, Osvaldo,Sandoval, Sydia
, p. 15 - 24 (2007/10/02)
The generation of α-silyl-α-borylmethane derivatives as intermediates and their oxidation to α-hydroxyorganosilanes is reported.The formation of the intermediate α-silyl-α-borylmethane derivatives is via the type I transfer reaction of organoboranes with either (trimethylsilyl)bromomethyllithium and (phenyldimethylsilyl)chloromethyllithium in THF or in some cases hexane.