7608-31-3Relevant articles and documents
Polycarbon ligands: Synthesis and characterization of the phosphinodiynes Ph2PC≡C-C≡CR (R = But, Ph, SiMe3),the μ-η1,η2α, β-butadiynyl complexes Ru2(CO)6-(μ-PPh 2
Blenkiron, Peter,Corrigan, John F.,Pilette, Didier,Taylor, Nicholas J.,Carty, Arthur J.
, p. 2349 - 2362 (2007/10/03)
The phosphino-diynes (PPh2C≡C-C≡CR) (R = But, Ph, SiMe3) are obtained in excellent yield from the corresponding diyne anions RC≡C-C≡C- by quenching with PPh2Cl. Monosubstitution on Ru3(CO)