76093-80-6Relevant articles and documents
The Thermolysis of Heterocyclic Aminimines
Posvic, Harvey,Meireles, Jorge C. de
, p. 1241 - 1243 (2007/10/02)
Aminimines derived from six heterocyclic tertiary amines were thermolyzed in t-butyl alcohol at ca. 80 deg.N-Methylindoline gave a good yield of the ring-opened product, and a double elimination on 1,4,4-trimethylpiperidine gave 3,3-dimethyl-1,4-pentadiene.The aminimine derived from quinuclidine was stable to elimination under these conditions.Simple elimination products were not obtained from N-methylpyrrolidine, N-methylpiperidine, or N-methyltetrahydroisoquinoline.
