7661-44-1

Basic information

• Product Name: 3-Heptanone, 2-phenyl-
• CAS NO: 7661-44-1
• Molecular Formula: C13H18O
• Molecular Weight: 190.285
• Mol File: 7661-44-1.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 3-Heptanone, 2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Heptanone, 2-phenyl-(7661-44-1)
• EPA Substance Registry System: 3-Heptanone, 2-phenyl-(7661-44-1)

Safety Data

• Hazardous Substances Data: 7661-44-1(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 71-41-0 pentan-1-ol 
• 110-62-3 pentanal 
• 98-86-2 acetophenone 
• 83021-59-4 (Z)-hept-2-en-2-ylbenzene 
• 25870-62-6 1-phenyl-2-hexanone 
• 74-88-4 methyl iodide 
• 1068-55-9 isopropylmagnesium chloride 
• 3156-07-8 methyl phenyl ketene 
• 25145-43-1 2-phenylpropionyl chloride 
• 492-37-5 hydratropic acid 
• 34713-70-7 2-Phenylpropanal 
• 110-59-8 pentanonitrile 
• 7695-69-4 bis(phenylthio)methylbenzene 

Downstream Products

• 56844-77-0 2-Phenylheptan-3-ol 
• 56844-72-5 2-Phenylheptan-3-ol 
• 114634-24-1 (2S,3S)-2-Phenyl-3-trimethylsilanyl-heptan-3-ol 
• 97234-89-4 (Z)-2-phenyl-3-trimethylsilyloxy-3-heptene 
• 97234-87-2 (E)-2-phenyl-3-trimethylsiloxy-3-heptene 
• 97234-85-0 (E)-2-phenyl-3-trimethylsilyloxy-2-heptene 

Relevant articles and documents

Direct Synthesis of Mono-α-arylated Ketones from Alcohols and Olefins via Ni-Catalyzed Oxidative Cross-Coupling

Controlled synthesis of α-monoarylated ketones is significant yet challenging due to the site-selectivity issues and nonproductive overarylation reactions. Herein, we reported the direct synthesis of α-arylated ketones enabled by Ni-catalyzed dehydrogenative cross-coupling reaction cascade between alcohols and olefins. The use of readily available and cost-effective alcohols and olefins provides a straightforward access to monoarylated ketones in good yields with exclusive selectivity without using any advanced synthetic intermediates.

Isomerization of terminal epoxides by a [Pd-H] catalyst: A combined experimental and theoretical mechanistic study

An unusual palladium hydride complex has been shown to be a competent catalyst in the isomerization of a variety of terminal and internal epoxides. The reaction displayed broad scope and synthetic utility. Experimental and theoretical evidence are provided for an unprecedented hydride mechanism characterized by two distinct enantio-determining steps. These results hold promise for the development of an enantioselective variant of the reaction.

Biocatalysed concurrent production of enantioenriched compounds through parallel interconnected kinetic asymmetric transformations

Parallel interconnected kinetic asymmetric transformations were performed in order to obtain enantioenriched derivatives starting from a set of racemic or prochiral compounds. Thus, in a one-pot reaction using two redox biocatalysts (a BVMO and an ADH) and a catalytic amount of cofactor that acts as a mediator, enantioenriched ketones, sulfoxides, and sec-alcohols were concurrently obtained in a strict parallel way, minimising the quantity of reagents employed. By selecting the appropriate biocatalysts, this methodology represents a potential tool for performing stereodivergent transformations.