76700-77-1

Basic information

• Product Name: 2'-O-<(phenoxythio)carbonyl>-3',5'-O-(1,1,3,3-tetraisopropyl-1,3-disiloxanediyl)adenosine
• Synonyms: 2'-O-<(phenoxythio)carbonyl>-3',5'-O-(1,1,3,3-tetraisopropyl-1,3-disiloxanediyl)adenosine
• CAS NO: 76700-77-1
• Molecular Weight: 645.927
• Mol File: 76700-77-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2'-O-<(phenoxythio)carbonyl>-3',5'-O-(1,1,3,3-tetraisopropyl-1,3-disiloxanediyl)adenosine(CAS DataBase Reference)
• NIST Chemistry Reference: 2'-O-<(phenoxythio)carbonyl>-3',5'-O-(1,1,3,3-tetraisopropyl-1,3-disiloxanediyl)adenosine(76700-77-1)
• EPA Substance Registry System: 2'-O-<(phenoxythio)carbonyl>-3',5'-O-(1,1,3,3-tetraisopropyl-1,3-disiloxanediyl)adenosine(76700-77-1)

Safety Data

• Hazardous Substances Data: 76700-77-1(Hazardous Substances Data)

Upstream product

• 58-61-7 adenosine 
• 108-95-2 phenol 
• 69304-37-6 1,3-Dichloro-1,1,3,3-tetraisopropyldisiloxane 
• 18043-71-5 1,1,3,3-tetraisopropyldisiloxane 
• 18173-84-7 diisopropylsilanol 
• 69304-45-6 3',5'-O-(1,1,3,3-tetra-isopropyldisiloxane-1,3-diyl)adenosine 
• 1005-56-7 phenylcarbonochloridothioate 

Downstream Products

• 1276113-10-0 N6-benzoyl-2'-deoxy-α-C-(1-phenylethane-1,2-diol)-3',5'-O-(1,1,3,3-tetraisopropyldisiloxan-1,3-diyl)adenosine 
• 1276113-12-2 N6-benzoyl-2'-deoxy-2'-C-α-(hydroxymethyl)-3',5'-O-(1,1,3,3-tetraisopropyldisiloxan-1,3-diyl)adenosine 
• 958-09-8 2'-deoxy-D-adenosine 

Relevant articles and documents

A solid-state deuterium NMR study of furanose ring dynamics in [d(CGCGAATTCGCG)]2

Solid-state deuterium NMR spectroscopy has been used to characterize the dynamics of the furanose rings of A5 and A6 (and by symmetry A17 and A18) in the self-complementary DNA dodecamer duplex [d(CGCGAATTCGCG)]2, which contains the EcoRI bindi

Synthesis of 2'-Allyl-2'-Deoxynucleosides by Radical Reactions

2'-α-Allyl-2'-deoxynucleosides derived from uridine, cytidine, adenosine and guanosine have been synthesized in high overall yields by photolysis of appropriately protected 2'-O-phenoxythiocarbonyl derivatives in the presence of allyltributylstannane.The 2'-allyl-2'-deoxynucleosides were 5'-O-DMT-protected and converted into 2'-deoxynucleoside 3'-O-phosphoramidites to serve as monomers for oligonucleotides.

Smooth and Efficient Deoxygenation of Secondary Alcohols. A General Procedure for the Conversion of Ribonucleosides to 2'-Deoxynucleosides

-