76859-15-9

Basic information

• Product Name: 9-Allyljulolidine
• Synonyms: 9-Allyljulolidine
• CAS NO: 76859-15-9
• Molecular Weight: 213.323
• Mol File: 76859-15-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 9-Allyljulolidine(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Allyljulolidine(76859-15-9)
• EPA Substance Registry System: 9-Allyljulolidine(76859-15-9)

Safety Data

• Hazardous Substances Data: 76859-15-9(Hazardous Substances Data)

Upstream product

• 479-59-4 julolidine 
• 93033-82-0 4-Allyl-9-methoxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolinium; iodide 
• 93033-84-2 4-Allyl-9-ethoxy-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolinium; bromide 
• 76859-16-0 4-Allyl-9-methoxyjulolidinium bromide 
• 93033-85-3 4-Allyl-9-bromo-2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolinium; bromide 
• 76859-14-8 N-allyljulolidinium bromide 
• 76859-24-0 N-allyljulolidinium iodide 

Relevant articles and documents

Amino-Claisen Rearrangement. IV. Quaternary Amino-Claisen Rearrangement of N-Allyljulolidinium Derivatives

The amino-Claisen rearrangements of 9-unsubstituted and 9-substituted N-allyljulolidinium halides were investigated.The former compounds can be regarded as aniline derivatives in which the two ortho sites are occupied.In the latter compounds, the two ortho positions and the para position are all blocked.N-Allyljulolidinium halides rearranged into 9-allyljulolidine.However, 9-substituted N-allyljulolidinium halides gave 8-allyl-9-substituted julolidines.This meta rearrangement constitutes the first reported example of meta amino-Claisen rearrangement.The reaction pathways can be rationalized in terms of a combination of and sigmatropic rearrangements.Keywords - amino-Claisen rearrangement; meta-rearrangement; N-allyljulolidinium halide; 9-substituted-N-allyljulolidinium halide; 9-allyljulolidine; 8-allyl-9-substituted julolidine; sigmatropic rearrangement; sigmatropic rearrangement