769-70-0Relevant articles and documents
Zeolite-catalyzed acetalization reaction of furfural with alcohol under solvent-free conditions
Jin, Fuxiang,Liu, Hailong,Liu, Qiao,Song, Heyuan
, (2021/08/09)
Acetalization reactions present a viable method for producing valuable chemicals and protecting carbonyl functionalities in organic compounds. Herein, several commercial zeolites were used as solid acid catalysts in the acetalization of biomass-derived furfural with alcohols under solvent-free conditions. The effects of major reaction parameters such as catalyst concentration, reaction temperature, and reaction time were investigated. Among the tested catalysts, SAPO-34 with appropriate acid sites and textural structure exhibited the highest catalytic activity under optimized reaction conditions. Additionally, the catalyst showed excellent recyclability and no obvious deactivation was observed even after using it six times.
Direct anodic (thio)acetalization of aldehydes with alcohols (thiols) under neutral conditions, and computational insight into the electrochemical formation of the acetals
Liu, Caiyan,Shen, Yongli,Xiao, Zihui,Yang, Hui,Han, Xue,Yuan, Kedong,Ding, Yi
, p. 4030 - 4034 (2019/08/07)
A versatile protocol for the production of acetals/thioacetals by means of direct electrochemical oxidation is developed here under neutral conditions, providing (thio)acetals with good functional group tolerance and a wide scope for both aldehydes and (thio)alcohols. DFT calculations reveal that direct electron transfer from the anode plays a key role in carbonyl activation during this acid free acetalization process.
PRODUCTION METHOD OF ALCOHOL
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Paragraph 0136; 0141, (2018/05/26)
PROBLEM TO BE SOLVED: To provide a production method of alcohol, which can obtain alcohol that is a target at a high yield while suppressing a side reaction and has long term operation stability when producing alcohol from a biomass raw material. SOLUTION: When producing alcohol from a biomass raw material, a method in which alcohol is produced via an acetal intermediate having a furan skeleton is provided. Alcohol is produced by producing an acetal intermediate and by undergoing a step of hydrogenating this with hydrogen gas. SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2018,JPOandINPIT