76927-63-4

Basic information

• Product Name: N⁴--N¹,N⁸-bis<2,3-(methylenedioxy)benzoyl>spermidine
• CAS NO: 76927-63-4
• Molecular Weight: 618.643
• Mol File: 76927-63-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N⁴--N¹,N⁸-bis<2,3-(methylenedioxy)benzoyl>spermidine(CAS DataBase Reference)
• NIST Chemistry Reference: N⁴--N¹,N⁸-bis<2,3-(methylenedioxy)benzoyl>spermidine(76927-63-4)
• EPA Substance Registry System: N⁴--N¹,N⁸-bis<2,3-(methylenedioxy)benzoyl>spermidine(76927-63-4)

Safety Data

• Hazardous Substances Data: 76927-63-4(Hazardous Substances Data)

Upstream product

• 73038-05-8 N-(3-aminobutyl)-N-(3-aminopropyl)(phenylmethyl)amine 
• 76927-64-5 N⁴-Benzyl-N¹,N⁸-bis<2,3-(methylenedioxy)benzoyl>spermidine hydrochloride 
• 66411-55-0 2,3-(Methylenedioxy)benzoyl chloride 
• 76927-61-2 N¹,N⁸-Bis<2,3-(methylenedioxy)benzoyl>spermidine 
• 77409-72-4 glycyl>trifluoroacetic anhydride 

Downstream Products

• 76927-62-3 3-<(2,3-dihydroxybenzoylamino)propyl>-N-<4-(2,3-dihydroxy-benzoylamino)butyl>-2-hydroxybenzoyl-glycylamide 

Relevant articles and documents

Biomimetic Synthesis of a Paracoccus denitrificans Siderophore Analogue

A biomimetic approach to the synthesis of N4-acylated N1,N8-bis(2,3-dihydroxybenzoyl)spermidine siderophores is described.The key to the sequence is the use of Cu(II) as a transitory protecting group for the catechols of N1,N8-bis(2,3-dihydroxybenzoyl)spermidine in the condensation of this synthon with the model acylating agent N-(2-hydroxybenzoyl)glycine.An alternative route to this siderophore analogue employing classical methods is offered as proof of structure.Preliminary investigations aimed at characterizing the chelate of interest are also described.Proton NMR paramagnetic line broadening studies confirm the catechols of N1,N8-bis(2,3-dihydroxybenzoyl)spermidine to be the chelating functionality.The stoichiometry of the complex is determined by spectrophotometric methods while the cumulative formation constants of the various protonated species are established by potentiometric techniques.