77-63-4Relevant articles and documents
Vardosanidze et al.
, p. 583,587 (1969)
Tandem-reduction of DMF with silanes via necklace-type transition over Pt(0) nanoparticles: Deciphering the dual Si-H effect as an extension of steric effects
Taori, Vijay P.,Buchmeiser, Michael R.
supporting information, p. 14820 - 14823 (2015/02/19)
Dimethylformamide (DMF) undergoes double-reduction to yield trimethylamine as a result of the concerted activation of DMF by two Si-H bonds (from different Si atoms) over Pt(0) nanoparticles as catalytic centers. Sterics on the Si atom govern the reaction and are also decisive for the structure of siloxane products due to potential limitations on the concerted activation. This journal is
A facile and efficient synthesis of organocyclosiloxanes
Zuev, Vjacheslav V.,Kalinin, Alexei V.
, p. 1289 - 1294 (2007/10/03)
A new facile preparative method for the synthesis of organocyclosiloxanes is reported. Ring closure of the dichlorosilanes with NaHCO3 and pyridine gave mixture of organocyclosiloxanes with cyclotrisiloxane as a main product.