773-53-5Relevant articles and documents
Study on the pyrolysis characteristics of a series of fluorinated cyclopentenes and implication of their environmental influence
Bi, Fang,Gao, Rui,Ji, Yuanyuan,Li, Hong,Li, Ling,Liu, Chenfei,Wang, Xuezhong,Wu, Zhenhai,Yanqin, Ren,Zhang, Hao,Zhang, Xin
, (2020/12/28)
3,3,4,4,5,5-hexafluorocyclopentene (6FE), 1,3,3,4,4,5,5-heptafluorocyclopentene (7FE) and octafluorocyclopentene (8FE) are considered as new generation of potential chlorofluorocarbons substitutes. To investigate the thermostabilities, tubular furnace experiments were designed over temperature range of 500-850℃. The results show that 6FE, 7FE and 8FE are all stable below 650 ℃, thus have good stabilities in common storage and practical use condition. Furthermore, considering the short atmospheric lifetimes (several months), low global warming potentials (GWPs, less than 119) and zero ozone depletion potentials (ODPs), the compounds seem no big influences on the climate change.
Bis(perfluoroorganyl)bromonium salts [(RF)2Br]Y (RF = aryl, alkenyl, and alkynyl)
Frohn, Hermann-Josef,Giesen, Matthias,Welting, Dirk,Bardin, Vadim V.
experimental part, p. 922 - 932 (2010/10/03)
Bromonium salts [(RF)2Br]Y with perfluorinated groups RFC6F5, CF3CFCF, C 2F5CFCF, and CF3C≡C were isolated from reactions of BrF3 with RFBF2 in weakly coordinating solvents (wcs) like CF3CH2CHF2 (PFP) or CF3CH2CF2CH3 (PFB) in 30-90% yields. C6F5BF2 formed independent of the stoichiometry only [(C6F5)2Br][BF 4]. 1:2 reactions of BrF3 and silanes C6F 5SiY3 (Y = F, Me) ended with different products - C 6F5BrF2 or [(C6F5) 2Br][SiF5] - as pure individuals, depending on Y and on the reaction temperature (Y = F). With C6F5SiF3 at ≥-30 °C [(C6F5)2Br][SiF5] resulted in 92% yield whereas the reaction with less Lewis acidic C 6F5SiMe3 only led to C6F 5BrF2 (58%). The interaction of K[C6F 5BF3] with BrF3 or [BrF2][SbF 6] in anhydrous HF gave [(C6F5) 2Br][SbF6]. Attempts to obtain a bis(perfluoroalkyl) bromonium salt by reactions of C6F13BF2 with BrF3 or of K[C6F13BF3] with [BrF2][SbF6] failed. The 3:2 reactions of BrF3 with (C6F5)3B in CH2Cl2 gave [(C6F5)2Br][(C6F 5)nBF4-n] salts (n = 0-3). The mixture of anions could be converted to pure [BF4]- salts by treatment with BF3·base.
ACTION OF VANADIUM AND ANTIMONY PENTAFLUORIDES ON POLYFLUORINATED DERIVATIVES OF CYCLOHEXADIENE
Avramenko, A. A.,Bardin, V. V.,Furin, G. G.,Karelin, A. I.,Krasil'nikov, V. A.,Tushin, P. P.
, p. 1298 - 1303 (2007/10/02)
Polyfluorinated 1,3- and 1,4-cyclohexadienes are fluorinated by vanadium fluoride at -25 to 25 deg C.The olefinic fragments of perfluoro-1,3- and perfluoro-1,4-cyclohexadienes are close to each other in reactivity.Under the influence of vanadium pentafluoride the fluorine atoms add to 1-R-heptafluoro-1,4-cyclohexadienes preferentially at the multiple bond containing the less electron-withdrawing substituent.At -80 to 20 deg C antimony pentafluoride leads to isomerization of the polyfluorinated derivatives of cyclohexadiene.