77312-73-3

Basic information

• Product Name: 2-Butanol, 3-(phenylmethoxy)-
• CAS NO: 77312-73-3
• Molecular Formula: C11H16O2
• Molecular Weight: 180.247
• Mol File: 77312-73-3.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 2-Butanol, 3-(phenylmethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanol, 3-(phenylmethoxy)-(77312-73-3)
• EPA Substance Registry System: 2-Butanol, 3-(phenylmethoxy)-(77312-73-3)

Safety Data

• Hazardous Substances Data: 77312-73-3(Hazardous Substances Data)

Upstream product

• 53346-05-7 2-(benzyloxy)propanal 
• 2747-38-8 methyltrichlorotitanium 
• 917-54-4 methyllithium 
• 75-16-1 methylmagnesium bromide 
• 97203-22-0 (-)-(S)-3-(phenylmethoxy)-2-butanone 
• 113133-46-3 3-(phenylmethoxy)butan-2-one 
• 273400-78-5 (4R,5S)-4,5-dimethyl-2-phenyl-1,3-dioxolane 
• 100-44-7 benzyl chloride 
• 513-85-9 2.3-butanediol 
• 100-39-0 benzyl bromide 

Downstream Products

• 93154-70-2 2-Benzyloxy-3-butyloxymethoxy-butan 
• 94327-73-8 3-(2-Benzyloxy-1-methyl-propyloxy)-propionsaeure-methylester 
• 92372-12-8 2-Ethoxymethoxy-3-benzyloxy-butan 
• 92500-93-1 3-(2-Benzyloxy-1-methyl-propyloxy)-propionsaeure-nitril 
• 93160-59-9 Diethyl-<(2-benzyloxy-1-methyl-propyloxy)-methyl>-amin 
• 91905-86-1 2-Benzyloxy-3-methoxymethoxy-butan 
• 94435-44-6 2-Benzyloxy-3-heptyloxymethoxy-butan 
• 93541-42-5 2-Benzyloxy-3-isopentyloxymethoxy-butan 
• 93154-71-3 2-Benzyloxy-3-isobutyloxymethoxy-butan 
• 94092-41-8 2-Benzyloxy-3-isopropyloxymethoxy-butan 
• 92860-68-9 2-Benzyloxy-3-propyloxymethoxy-butan 
• 94259-51-5 2-Benzyloxy-3-hexyloxymethoxy-butan 
• 93541-43-6 2-Benzyloxy-3-pentyloxymethoxy-butan 

Relevant articles and documents

Reductive cleavage of acetals and ketals with 9-borabicyclo[3.3.1]nonane

The reductive cleavage of benzaldehyde acetals and acetophenone ketals with the air-stable crystalline 9-borabicyclo[3.3.1]-nonane dimer provides monobenzylated ether derivatives of diols and 1,2-oxygen-transposed β-phenethyl alcohols, respectively. The boron moiety is effectively recovered through simple procedures which involve convenient air-stable reagents and boron byproducts. The process is particularly selective for 1,3-diols giving the more substituted monobenzyl ether derivatives exclusively. With acetophenone ketals both reduction and elimination occur, permitting 9-BBN-H to hydroborate the resulting styrene to produce 1,2-oxygen-transposed β-phenethyl alcohols cleanly. Potential applications of this new process were illustrated with the synthesis of the hallucinogen, mescaline, and the analgesic, ibufenac.

Hydrogenation of α-Keto Ethers: Dynamic Kinetic Resolution with a Heterogeneous Modified Catalyst and a Heterogeneous Base

The first successful example of the asymmetric hydrogenation of substituted α-keto ethers with Cinchona-modified Pt/Al2O3 is reported. In the absence of an additional base, kinetic resolution of the racemic starting material was observed with high diastereoselectivity and ee's up to 98% at conversions of a strong reaction acceleration but racemic product. Immobilization of OH- on solid ion exchangers resulted in the desired dynamic kinetic resolution, and ee's of >80% were obtained at >95% conversion. These effects are rationalized on the basis of a simple kinetic and structural model.

Methylaluminum bis(4-substituted-2,6-di-tert-butylphenoxide) as an efficient nonchelating Lewis acid: Application to asymmetric Diels-Alder reaction and diastereoselective alkylation to alkoxy carbonyl substrates

The exceptionally bulky methylaluminum bis(4-substituted-2,6-di-tert-butylphenoxide) such as MAD or MABR can be successfully utilized as a highly efficient nonchelating Lewis acid for achieving high stereoselectivity in 1,n asymmetric induction in cyclic