7758-95-4Relevant articles and documents
Reactions of tin and lead with tricarbonylcyclopentadienylmolybdenum(II) and tricarbonylcyclopentadienyltungsten(II) chlorides
Piskunov,Maslennikov,Spirina,Maslennikov,Artemov
, p. 65 - 67 (2002)
Tin was oxidized with tricarbonylcyclopentadienylmolybdenum and tricarbonylcyclopentadienyl-tungsten chlorides to obtain polynuclear organometallic compounds [η5-C5H5M(CO) 3]2SnCl2 (M = Mo,
Ba6BO3Cl9and Pb6BO4Cl7: structural insights intoortho-borates with uncondensed BO4tetrahedra
Li, Wei,Wu, Hongping,Yu, Hongwei,Hu, Zhanggui,Wang, Jiyang,Wu, Yicheng
, p. 6086 - 6089 (2020)
Two new halogen-richortho-borates, Ba6BO3Cl9and Pb6BO4Cl7, were synthesized and characterized. Interestingly, Pb6BO4Cl7contains rare uncondensed BO4/s
Baxter, G. P.,Wilson, J. H.
, p. 187 - 195 (1908)
Willard, H. H.,Kassner, J. L.
, p. 2391 - 2396 (1930)
A Monoaryllead Trichloride That Resists Reductive Elimination
Olaru, Marian,Kather, Ralf,Hupf, Emanuel,Lork, Enno,Mebs, Stefan,Beckmann, Jens
, (2018)
Transmetallation of Pb(OAc)4 with R2Hg (1), followed by treatment with HCl in Et2O, provided RPbCl3 (2), the first kinetically stabilized monoorganolead trihalide that resists reductive elimination under ambient
Moore, W. C.
, p. 1091 - 1091 (1911)
The synthesis, characterization, and theoretical analysis of (NH4)3PbCl5
Zhu, Liang,Jin, Wenqi,Yang, Zhihua,Yang, Yun,Pan, Shilie
, p. 2038 - 2043 (2021)
A new compound, namely (NH4)3PbCl5, has been synthesized via a low-temperature molten salt method in a closed system. It crystallizes in the orthorhombicPnma(No. 62) space group. The crystal structure of (NH4)3PbCl5features a distinct three-dimensional network constructed via hydrogen bonds that exist between ammonium and chloride anions. The UV-Vis-NIR diffuse reflectance spectrum displays a short UV cutoff edge at about 256 nm. Besides, the thermal behavior (TG and DSC) was also analyzed. To better understand the structure-property relationships of (NH4)3PbCl5, theoretical calculations based on density functional theory were also performed. The result shows that the birefringence is expected to be about 0.050 at 1064 nm, and the bandgap is about 4.45 eV, which is consistent with the experimental result.
Bhat, H. L.
, (1981)
FCC-HCP phase boundary in lead
Kuznetsov,Dmitriev,Dubrovinsky,Prakapenka,Weber
, p. 125 - 127 (2002)
The temperature evolution of fcc-to-hcp transformation in lead metal was studied and pressure-temperature equation of state for fcc and hcp phases up to 800 K and 40 GPa was determined. Polycrystalline lead was studied in extremely heated, gasketed diamond anvil cell. In situ high-pressure-high-temperature data were obtained at the ID-30 beam line by angle dispersive X-ray diffraction techniques employing monochromatic X-radiation. An unexpected interaction of lead with sodium chloride surrounded the samples and significant reduction of the alloying temperature with gold was observed.
Copper polytellurite-chlorides with A2?+ cations ([Formula presented], Pb) obtained by CVT reactions
Zinyakhina, Diana O.,Siidra, Oleg I.,Charkin, Dmitri O.,Nazarchuk, Evgeniy V.,Bubnova, Rimma S.
, p. 94 - 97 (2016)
Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8?+ one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.
Novel cubic gravel-like EDAPbCl4@ZIF-67 as electrochemical sensor for the detection of protocatechuic acid
Chen, Kaixuan,Li, Shuji,Luo, Shiping,Song, Ningning,Su, Zilong,Wang, Jiajun,Xie, Aijuan,Yang, Yun,Zhu, Shichao
, (2022/02/03)
A novel EDAPbCl4 @ZIF-67 (EDA = ethylenediammonium) nanocomposite material was successfully prepared by embedding a hybrid organic-inorganic perovskites (HOIPs) into a porous zeolite imidazolate frame structure material (Zeolitic Imidazolate Frameworks, ZIFs). The electrochemical sensor was fabricated through dropping EDAPbCl4 @ZIF-67 onto the surface of glassy carbon electrode (GCE) and applied to the detection of protocatechuic acid (PCA). The results of a series of electrochemical performance tests including cyclic voltammetry (CV) and differential pulse voltammetry (DPV) showed that EDAPbCl4 @ZIF-67/GCE could amplify the signal of the electrochemical response to the oxidation of PCA. The peak current of EDAPbCl4 @ZIF-67/GCE was linearly increased with the concentration in the range of 22–337 μM. The linear regression equation was I(μA)= 0.0031 C (μM)+ 1.6968 (R2 =0.9916), the detection limit (S/N = 3) was 15 μM. Meanwhile, EDAPbCl4 @ZIF-67/GCE can effectively detect PCA in green tea and cough syrup.Its relatively excellent sensitivity indicated that the hybrid organic-inorganic perovskite (EDAPbCl4 @ZIF-67) was feasible to be used as electrochemical sensor material.