78833-98-4

Basic information

• Product Name: Hydroperoxide, 1-phenylethyl, (R)-
• Synonyms: (R)-1-Phenyl-eth-1-yl-hydroperoxide;(R)-1-Phenyl-aethylhydroperoxid;(R)-1-phenyl-ethyl hydroperoxide
• CAS NO: 78833-98-4
• Molecular Formula: C8H10O2
• Molecular Weight: 138.166
• Mol File: 78833-98-4.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 66 °C (0.5 mmHg)
• Density: 1.089±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Hydroperoxide, 1-phenylethyl, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydroperoxide, 1-phenylethyl, (R)-(78833-98-4)
• EPA Substance Registry System: Hydroperoxide, 1-phenylethyl, (R)-(78833-98-4)

Safety Data

• Hazardous Substances Data: 78833-98-4(Hazardous Substances Data)

Upstream product

• 3071-32-7 1-phenylethyl hydroperoxide 
• 1445-91-6 (S)-1-phenylethanol 
• 98-85-1 1-Phenylethanol 
• 1517-69-7 (R)-1-phenylethanol 

Downstream Products

• 21243-93-6 ((S)-1-phenyl-ethyl)-xanthen-9-yl peroxide 
• 21243-93-6 ((R)-1-phenyl-ethyl)-xanthen-9-yl peroxide 
• 591-50-4 iodobenzene 
• 1445-91-6 (S)-1-phenylethanol 
• 98-86-2 acetophenone 
• 14371-10-9 (E)-3-phenylpropenal 
• 21915-53-7 2,3-epoxy-3-phenyl-1-propanol 
• 100-52-7 benzaldehyde 
• 79144-42-6 (R)-(+)-α-phenethyl triphenylmethyl peroxide 

Relevant articles and documents

Biocatalytic kinetic resolution of racemic hydroperoxides through the enantioselective reduction with free and immobilized microorganisms

A Bacillus subtilis strain, isolated from topsoil by a selective screening procedure, is effective for the biocatalytic kinetic resolution of racemic hydroperoxides. A variety of secondary aralkyl hydroperoxides have been resolved by this microorganism in

Kinetic resolution of hydroperoxides with enantiopure phosphines: Preparation of enantioenriched tertiary hydroperoxides

An efficient reductive kinetic resolution strategy capable of accessing optically active tertiary hydroperoxides is reported. Readily accessible tertiary hydroperoxides are resolved with commercially available (R)- or (S)-xylyl-PHANEPHOS with selectivity factors as large as 37. The resulting bis(phosphine oxide) can be recycled in high yields. The isolated mono(phosphine oxide) intermediate resolved hydroperoxides with the same selectivity as the parent bisphosphine. Copyright

Kinetic resolution of chiral hydroperoxides: hydrogen-peroxide-mediated screening of peroxidase-active soil bacteria

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