791-30-0Relevant articles and documents
Boron-metal exchange reaction of silylboranes with organometallic reagents: A new route to arylsilyl anions
Kawachi, Atsushi,Minamimoto, Takashi,Tamao, Kohei
, p. 1216 - 1217 (2007/10/03)
The boron-metal exchange reaction of (arylsilyl)boranes with alkyllithiums, potassium tert-butoxide, and methylmagnesium bromide affords the corresponding silyllithium, silylpotassium, and silylmagnesium compounds, respectively. Especially, the boron-lithium exchange reaction occurs even in hydrocarbon solvents such as toluene and hexane as well as in THF.