792-68-7

Basic information

• Product Name: o-Dibenzylbenzene
• Synonyms: a,a-Diphenyl-o-xylene
• CAS NO: 792-68-7
• Molecular Formula: C₂₀H₁₈
• Molecular Weight: 258.36
• Mol File: 792-68-7.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: o-Dibenzylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: o-Dibenzylbenzene(792-68-7)
• EPA Substance Registry System: o-Dibenzylbenzene(792-68-7)

Safety Data

• Hazardous Substances Data: 792-68-7(Hazardous Substances Data)

Upstream product

• 101-81-5 Diphenylmethane 
• 38632-84-7 benzyl benzenesulfonate 
• 4301-15-9 ethynyldimagnesium dibromide 
• 100-39-0 benzyl bromide 
• 71-43-2 benzene 
• 100-44-7 benzyl chloride 
• 104-15-4 toluene-4-sulfonic acid 
• 100-51-6 benzyl alcohol 
• 109-87-5 Dimethoxymethane 
• 767-90-8 (2-ethylphenyl)methanol 
• 612-14-6 phthalyl alcohol 
• 91-13-4 α,α'-dibromo-o-xylene 
• 62673-31-8 benzyl(bromo)zinc 
• 583-53-9 2,3-dibromobenzene 

Downstream Products

• 85-52-9 2-Benzoylbenzoic acid 
• 1159-86-0 o-dibenzoylbenzene 
• 792-67-6 1,2-Bis-cyclohexylmethyl-cyclohexan 
• 102159-74-0 1,2,3,4,10-Pentabrom-1,2,3,4-tetrahydro-9-phenylanthracen 
• 102024-99-7 α,α'-diphenylphthalyl bromide 
• 964-46-5 trans-1,2-diphenyl-1,2-dihydrocyclobutabenzene 

Relevant articles and documents

Nickel-Catalyzed Cross-Coupling of Anisoles with Alkyl Grignard Reagents via C-O Bond Cleavage

Nickel-catalyzed cross-coupling of methoxyarenes with alkyl Grignard reagents, which involves the cleavage of the C(aryl)-OMe bond, has been developed. The use of 1,3-dicyclohexylimidazol-2-ylidene as a ligand allows the introduction of a variety of alkyl groups, including Me, Me3SiCH2, ArCH2, adamantyl, and cyclopropyl. The method can also be used for the alkylative elaboration of complex molecules bearing a C(aryl)-OMe bond.

TRANSITION METAL CATALYSTS FOR C-O HYDROGENOLYSIS AND HYDRODEOXYGENATION

Phosphoranimide-metal catalysts and their role in C—O bond hydrogenolysis and hydrodeoxygenation (HDO) are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze C—O bond hydrogenolyses of a range of oxygen-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodeoxygenation.

Palladium catalyzed ligand-free Suzuki cross-coupling reactions of benzylic halides with aryl boronic acids under mild conditions

A highly efficient Suzuki cross-coupling reaction between benzylic halides and aryl boronic acids using palladium chloride as catalyst in acetone:water (3:1) has been developed. High yields of products, mild reaction conditions and short reaction times in the absence of ligand are important features of this method. A highly efficient Suzuki cross-coupling reaction between benzylic halides and aryl boronic acids using palladium chloride as catalyst in acetone:water (3:1) as the solvent system has been developed. High yields of products, mild reaction conditions and short reaction times in the absence of ligand are important features of this method.