79269-71-9

Basic information

• Product Name: BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE
• Synonyms: BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE;BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM(IV) DICHLORIDE;BIS(TERTBUTYLCYCLOPENTADIENYL) TIANIUM DICHLORIDE;BIS(TERT-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE;BIS-(BUTYLCYCLOPENTADIENYL)-DICHLOROTITANIUM(IV);Bis(t-butylcyclopentadienyl)titaniumdichloride,min.98%;bis(tert-butylcyclopentadienyl)titanium(iv) dichloride;BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE, MIN.
• CAS NO: 79269-71-9
• Molecular Formula: C₁₈H₂₆Cl₂Ti
• Molecular Weight: 361.17
• Product Categories: organometallic complex
• Mol File: 79269-71-9.mol
• Article Data: 3

Chemical Properties

• Melting Point: 233 °C(lit.)
• Appearance: red/crystal
• Sensitive: Air & Light Sensitive
• CAS DataBase Reference: BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE(79269-71-9)
• EPA Substance Registry System: BIS(T-BUTYLCYCLOPENTADIENYL)TITANIUM DICHLORIDE(79269-71-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26
• WGK Germany: 3
• TSCA: No
• Hazardous Substances Data: 79269-71-9(Hazardous Substances Data)

Usage

Chemical Properties

Bordeaux crystals

InChI:InChI=1/2C9H13.2ClH.Ti/c2*1-9(2,3)8-6-4-5-7-8;;;/h2*4,6H,5H2,1-3H3;2*1H;/q;;;;+2/p-2/rC18H26Ti.2ClH/c1-17(2,3)13-9-7-11-15(13)19-16-12-8-10-14(16)18(4,5)6;;/h7-10H,11-12H2,1-6H3;2*1H/q+2;;/p-2

Upstream product

• 10544-50-0 sulfur 
• 35059-40-6 t-butylcyclopentadiene 
• 7550-45-0 titanium tetrachloride 
• 50356-03-1 tert-butylcyclopentadienyl lithium 

Relevant articles and documents

STRUCTURE AND REACTIVITY OF SUBSTITUTED DI-η5-CYCLOPENTADIENYL METAL DIHALIDES. CRYSTAL STRUCTURE OF DICHLOROBIS(Η5-t-BUTYLCYCLOPENTADIENYL)ZIRCONIUM(IV)

A new approach to the synthesis of t-butylcyclopentadienyl and related anions, via the addition of methyl- or other alkyl-lithium compounds to dimethylfulvene, is reported and details are given for the preparation of (η5-t-BuCp)2ZrCl2 and (η5-t-BuCp)2TiCl2.The zirconium compound is orthorhombic, P21212, a 13.003(17), b 10.761(10), c 6.703(8) Angstroem.A crystal structure determination (R = 0.037, 980 reflections) shows that the t-butyl groups are directed away from each other on opposite sides of the molecule: this structure appears to be adopted only in molecules in which the substituent groups are too bulky to be accommodated directly above and below the MCl2 group.