793680-20-3Relevant articles and documents
Containing-containing layer C(sp2 Process)-N for the preparation of a bond-containing compound
-
Paragraph 0098-0101; 0105-0107, (2020/01/12)
The invention discloses a preparation method of a compound containing C (sp2)-N bonds as shown in a formula I. The preparation method includes the step: performing constant-current electrolysis reaction on a compound as shown in a formula II and a compoun
Copper-catalyzed carboxamide-directed ortho amination of anilines with alkylamines at room temperature
Li, Qiong,Zhang, Shu-Yu,He, Gang,Ai, Zhaoyan,Nack, William A.,Chen, Gong
supporting information, p. 1764 - 1767 (2014/04/17)
In this report, a highly efficient method for the room temperature installation of alkyl amino motifs onto the ortho position of anilines via Cu-catalyzed carboxamide-directed amination with alkylamines is described. This method offers a practical solution for the rapid synthesis of complex arylamines from simple starting materials and enables new planning strategies for the construction of arylamine-containing pharmacophores. A single electron transfer (SET)-mediated mechanism is proposed.