797057-70-6Relevant articles and documents
Synthesis, structures and charge?transfer complexations of 1,n-di-[3,6-di-(9-carbazolyl)-9-carbazolyl]alkanes with tetracyanoethylene and tetranitromethane
?zgün, Selin,Asker, Erol,Zeybek, Orhan
, p. 31 - 42 (2016/08/01)
Synthesis and charge?transfer (CT) complexations of amorphous 3,6-di-(9-carbazolyl)-9-ethylcarbazole, 3,6-di-(9-carbazolyl)-9-hexylcarbazole and a series of 1,n-di-[3,6-di-(9-carbazolyl)-9-carbazolyl]alkanes (n?=?1–5) with electron acceptors tetracyanoethylene and tetranitromethane are reported. The molar extinction coefficients (ε), equilibrium constants (Keq), enthalpies (ΔH) and entropies (ΔS) of complexations have been determined. The low Keq values (1.83–3.82?M?1 for carbazole?TCNE and 0.28–0.45?M?1 for carbazole?TNM complexes) show weak donor?acceptor associations. The negative values of ΔH determined to be between??2.09?±?0.08 and??3.10?±?0.21?kcal?mol?1 for carbazole?TCNE complexes and??0.91?±?0.08 and??3.31?±?0.28?kcal?mol?1 for carbazole?TNM complexes indicate that complexations are driven by the exothermic enthalpies. Computational analysis using semi?empirical and DFT methods were applied to clarify the structures of the synthesized molecules and the nature of their CT complexations.
Carbazole derivative, organic semiconductor element, light emitting element, and electronic device
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Page/Page column 17, (2008/06/13)
The problem of the present invention is to provide a carbazole derivative which has an excellent heat resistance and can be formed into a film without crystallization. Also, a problem is to produce an organic semiconductor element, a light emitting element and an electronic device by employing the carbazole derivative. For the purpose, a novel carbazole derivative represented by following general formula (1) is provided: (in the formula, I represents a core carbazole (G0) illustrated by general formula (2), Z represents an internally branched carbazole (G1 to Gn-1) illustrated by general formula (3), E represents an end carbazole (Gn) illustrated by general formula (4), n represents an integer showing generation number of dendrimer, X1 represents hydrogen, halogen, a cynano group, an alkyl group, an aryl group, a heterocyclic residue or the like, X2 and X3 in (G(n-m)-1) (provided, n-m≧1) make a covalent bond with X4 in (G(n-m)), and each of R1 to R8 represents independently hydrogen, halogen, a cynano group, an alkyl group, a dialkylamino group, a diarylamino group, a heterocyclic residue or the like).