79746-17-1 Usage
Purity
97% The compound has a high level of purity, which is important for its use in various chemical reactions and applications.
Isomers
Mixture of cis and trans The compound consists of a mixture of both cis and trans isomers, which can influence its reactivity and the types of products formed in chemical reactions.
Chemical structure
The compound has a butadiene backbone with a triethylsilyloxy group attached to the first carbon atom. This structure allows for the formation of carbon-carbon bonds and the addition of other functional groups.
Reactivity
The triethylsilyloxy group enhances the reactivity of the butadiene, making it a useful reagent in organic synthesis.
Applications
The compound is commonly used in the formation of carbon-carbon bonds, particularly in Diels-Alder reactions, and as a precursor for the preparation of various functionalized organic compounds.
Industries
It is utilized in pharmaceuticals, materials science, and other industries for the synthesis of complex organic molecules.
Functional groups
The triethylsilyloxy group facilitates the addition of the butadiene to other functional groups, enabling the formation of complex organic molecules.
Safety
As with any chemical compound, proper handling, storage, and disposal procedures should be followed to ensure safety and minimize environmental impact.
Check Digit Verification of cas no
The CAS Registry Mumber 79746-17-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 7,9,7,4 and 6 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 79746-17:
(7*7)+(6*9)+(5*7)+(4*4)+(3*6)+(2*1)+(1*7)=181
181 % 10 = 1
So 79746-17-1 is a valid CAS Registry Number.
79746-17-1Relevant articles and documents
Nickel-Catalyzed Enantioselective Synthesis of Pre-Differentiated Homoallylic syn- or anti-1,2-Diols from Aldehydes and Dienol Ethers
Davies, Thomas Q.,Murphy, John J.,Dousset, Maxime,Fürstner, Alois
supporting information, p. 13489 - 13494 (2021/09/11)
Nickel catalysis allied with cyclodiphosphazane or VAPOL-derived phosphoramidite ligands provides selective access to monoprotected vicinal diols by reductive coupling of dienol ethers and aldehydes. The observed regioselectivity is unprecedented, in that the diene reacts at the least nucleophilic and most hindered C atom that is attached to the oxygen substituent rather than at the terminal position. Notably, both syn and anti diastereomers of the products can be accessed depending on the configuration of the diene partner with usually excellent diastereo- and enantioselectivity.
Stereoselective Addition of Nucleophiles on α-Trialkylsilyl-β,γ-Unsaturated Aldehydes
Bideau, Franck Le,Gilloir, Fabienne,Nilsson, Ylva,Aubert, Corinne,Malacria, Max
, p. 1641 - 1644 (2007/10/02)
Palladium(0)-catalyzed rearrangement of silicon substituted vinyloxiranes is depending on the size of the trialkylsilyl groups.Addition of organolithium or Grignard reagents on α-trialkylsilyl-β,γ-unsaturated aldehydes furnished the corresponding alcohols
