80101-88-8

Basic information

• Product Name: 2,6,2',6'-tetramethylazoxybenzene
• CAS NO: 80101-88-8
• Molecular Weight: 254.332
• Mol File: 80101-88-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,6,2',6'-tetramethylazoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2,6,2',6'-tetramethylazoxybenzene(80101-88-8)
• EPA Substance Registry System: 2,6,2',6'-tetramethylazoxybenzene(80101-88-8)

Safety Data

• Hazardous Substances Data: 80101-88-8(Hazardous Substances Data)

Usage

Class

Azo compounds

Common uses

Radical initiator in polymerization reactions, particularly in the production of polystyrene and initiation of polymerization of methacrylate monomers for the production of plastic and rubber products

Physical form

Red to brown solid

Solubility

Insoluble in water, soluble in organic solvents

Safety precautions

Flammable, causes skin and eye irritation upon contact

Upstream product

• 87-62-7 2,6-dimethylaniline 
• 10228-76-9 (E)-1,2-bis(2,6-dimethylphenyl)diazene 
• 101225-69-8 2,6,2',6'-tetramethylazobenzene N,N'-dioxide 
• 81-20-9 2,6-dimethylnitrobenzene 
• 3096-63-7 N-(2,6-dimethylphenyl)hydroxylamine 

Downstream Products

• 10228-76-9 (E)-1,2-bis(2,6-dimethylphenyl)diazene 

Relevant articles and documents

Method for synthesizing oxidized azo compound through selective oxidation of aromatic amine

The invention discloses a method for synthesizing an oxidized azo compound through selective oxidation of an aromatic amine, wherein an aromatic amine is used as a raw material, hydrogen peroxide is used as an oxidizing agent, a titanium-silicon molecular sieve or a metal modified titanium-silicon molecular sieve is used as a catalyst, and the aromatic amine is subjected to selective catalytic oxidation to prepare the corresponding oxidized azobenzene compound. According to the present invention, the method has advantages of environmental protection, good selectivity, high product yield, easyseparation and recycling of the catalyst, simple instrument required by the reaction, and easy operation.

Silica encapsulated magnetic nanoparticles-supported Zn(II) nanocatalyst: A versatile integration of excellent reactivity and selectivity for the synthesis of azoxyarenes, combined with facile catalyst recovery and recyclability

A novel and highly efficient zinc based nanocatalyst has been synthesized by covalent grafting of 2-acetylpyridine on amine functionalized silica@magnetite nanoparticles, followed by metallation with zinc acetate. The resulting nano-composite was found to be highly efficient for oxidation of various aromatic amines to give azoxyarenes. The prepared nanocatalyst was characterized by Electron microscopy techniques (SEM and TEM with EDS), X-ray diffraction (XRD), vibrational sampling magnetometer (VSM), Fourier transform infrared spectroscopy (FT-IR) and atomic absorption spectroscopy (AAS) techniques. High turnover number (TON), mild reaction conditions and high selectivity for azoxyarenes with sustained catalytic activity makes present protocol worthy and highly compliant as compared to the other non-magnetic heterogeneous catalytic system. The acquisition of this nanocatalyst is also exemplified by employing the catalyst in leaching and reusability test and the results from the tests showing negligible zinc leaching and recycling was achieved multiple times just by sequestering using an external magnet.