808753-58-4Relevant articles and documents
Syntheses, structures and magnetic properties of Mn(II) dimers [CpMn(μ-X)]2 (Cp = C5H5; X= RNH, R 1R2N, C≡CR)
Alvarez, Carmen Soria,Boss, Sally R.,Burley, Jonathan C.,Humphry, Simon M.,Layfield, Richard A.,Kowenicki, Richard A.,McPartlin, Mary,Rawson, Jeremy M.,Wheatley, Andrew E.H.,Wood, Paul T.,Wright, Dominic S.
, p. 3481 - 3487 (2007/10/03)
Manganocene, Cp2Mn, has been employed as a precursor in the synthesis of a range of Mn(II) dimers of the type [CpMn(μ-X)]2 [X = 8-NHC9H6N (1), N(Ph)(C5H4N) (2), N(4-EtC6H4)(C5H4N) (3) and C≡CPh (4)] as well as the bis-adduct [Cp2Mn{HN=C(NMe 2)2}2] (5). The solid-state structures of 1-5 are reported. Variable-temperature magnetic measurements have been used to assess the extent of Mn(μ-X)Mn communication within the dimers of 1-4 as a function of the bridging ligands (X).