81360-89-6

Basic information

• Product Name: 2,2'-diseleno-bis(1-phenyl-2-methyl-1-propanone)-Se-oxide
• Synonyms: 2,2'-diseleno-bis(1-phenyl-2-methyl-1-propanone)-Se-oxide
• CAS NO: 81360-89-6
• Molecular Weight: 468.313
• Mol File: 81360-89-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2'-diseleno-bis(1-phenyl-2-methyl-1-propanone)-Se-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2'-diseleno-bis(1-phenyl-2-methyl-1-propanone)-Se-oxide(81360-89-6)
• EPA Substance Registry System: 2,2'-diseleno-bis(1-phenyl-2-methyl-1-propanone)-Se-oxide(81360-89-6)

Safety Data

• Hazardous Substances Data: 81360-89-6(Hazardous Substances Data)

Upstream product

• 81360-90-9 bis-(2-benzoyl-2-propyl) diselenide 
• 104722-60-3 3-benzyl-2,4-dioxo-3-pentyl 2-benzoyl-2-propyl selenide 
• 81360-96-5 1-phenyl-2-(chloroseleno)-2-methylpropanone 
• 81360-88-5 C₂₂H₂₄O₄Se 
• 103-49-1 dibenzylamine 
• 104722-78-3 C₂₀H₂₂O₃Se 
• 81360-92-1 2-benzoyl-2-propaneseleninic acid 
• 39158-85-5 2-methyl-1-phenyl-1-trimethylsiloxy-1-propene 

Downstream Products

• 104722-74-9 C₂₀H₂₂O₂Se₃ 
• 104722-58-9 N,N-dibenzyl 2-benzoyl-2-propane selenenamide 
• 104722-76-1 C₂₂H₂₄O₃Se 
• 104722-68-1 1-(1-benzoyl-2,2-dimethylcyclopropyl) 2-benzoyl-2-propylselenide 
• 104722-75-0 C₂₀H₂₀O₃Se 
• 104722-65-8 1-(1-benzoylcyclopropyl) 2-benzoyl-2-propyl selenide 
• 104722-78-3 C₂₀H₂₂O₃Se 
• 104722-59-0 bis-2-benzoyl-2-propyl selenide 
• 104722-57-8 methyl-d3 2-benzoyl-2-propaneseleneninate 
• 81360-92-1 2-benzoyl-2-propaneseleninic acid 
• 81360-96-5 1-phenyl-2-(chloroseleno)-2-methylpropanone 
• 769-60-8 2-methyl-1-phenylprop-2-en-1-one 
• 81360-91-0 N,N-dimethyl 2-benzoyl-2-propane selenenamide 
• 81360-90-9 bis-(2-benzoyl-2-propyl) diselenide 

Relevant articles and documents

ORGANOSELENIUM CHEMISTRY A STUDY OF INTERMEDIATES IN THE FRAGMENTATION OF ALIPHATIC KETOSELENOXIDES. CHARACTERIZATION OF SELENOXIDES, SELENENAMIDES AND SELENOLSELENINATES BY (1)H-, (13)C- AND (77)Se-NMR

A series of β-ketoselenenic acids was generated at low temperature (-20 deg C to -50 deg C) by selenoxide syn elimination of appropriate selenoxides (13-ox, 16-ox, 35-ox, 38-ox, and 39-ox).No evidence for the buildup of significant concentrations of selenenic acid was obtained.A selenolseleninate (15, 2,2'-diseleno-bis(1-phenyl-2-methyl-1-propanone)-Se-oxide) was detected as an intermediate in the decomposition of 13-ox and 16-ox.This compound, which is stable in solution below -50 deg C was characterized by NMR spectroscopy ( (1)H, (13)C, (77)Se ) and by its thermal decomposition and reactions with phosphite (reduction to diselenide 6) and dialkylamines (formation of selenenamide 11).Decomposition of 15 in the presence of dibenzylamine resulted in trapping of a selenenic acid-like species (RSeSeOH) to give RSeSeN(CH2Ph)2 (R=PhC(O)C(CH3)2).Although 15 could not be prepared by oxidation of diselenide 6, it was possible to prepare a cyclic selenolseleninate (4,4-dimethyl-1,2-diselenolane monooxide, 20) by oxidation of the related diselenide (19).Attempts to prepare more stable aliphatic selenenic acids by blocking the principal decomposition pathway of 15 were not successful.Thus 1-benzoyl-1-cyclopropaneselenenic acid was generated from 35-ox and 38-ox and 1-benzoyl-2,2-dimethylcyclopropaneselenenic from 39-ox.The former underwent normal disproportionation (to 36 and 37) even when prepared at -49 deg C.The latter gave what appeared to be a selenolseleninate (40) which again disproportionated at -17 deg C.