81385-41-3Relevant articles and documents
Orthoamides, XXXVI. - Formylation of 2,5-Dialkyl-1,3,4-thiadiazoles and 2,3,5-Trialkyl-1,3,4-thiadiazolium Salts by Orthoamides of Formic acid
Kantlehner, Willi,Haug, Erwin,Hagen, Helmut
, p. 298 - 305 (2007/10/02)
1,3,4-Thiadiazoles 6a-c react with the aminal-ester 2a to give the enamines 5a-c.Amide acetales 1 formylize the 1,3-dithia-5,6-diazepine 9 to yield the enamine 8.Treatment of 6 or 9 with two moles of 2a affords the di-enamines 7 and 10, respectively. 1,3,