81638-04-2

Basic information

• Product Name: 2-(Phenoxybenzoyl)-diphenylphosphin
• Synonyms: 2-(Phenoxybenzoyl)-diphenylphosphin
• CAS NO: 81638-04-2
• Molecular Weight: 382.398
• Mol File: 81638-04-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(Phenoxybenzoyl)-diphenylphosphin(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Phenoxybenzoyl)-diphenylphosphin(81638-04-2)
• EPA Substance Registry System: 2-(Phenoxybenzoyl)-diphenylphosphin(81638-04-2)

Safety Data

• Hazardous Substances Data: 81638-04-2(Hazardous Substances Data)

Upstream product

• 2243-42-7 2-phenoxybenzoic acid 

Downstream Products

• 90-47-1 xanth-9-one 
• 92-52-4 biphenyl 
• 19434-34-5 2-(phenoxy)benzaldehyde 

Relevant articles and documents

ORGANISCHE PHOTOCHEMIE XLIII. Diphenylphosphinigsaeure, Hetero- und Carbocyclen aus ortho-?-funktionalisierten Aroyl-Diphenylphosphinen durch UV-Bestrahlung in Loesung

New aroyl diphenyl phosphines (1f-i) substituted with ?-functions in ortho-positions of the aroyl part have been synthesized and photolyzed in benzene.In two cases (1h and i) 1.2- and 1.4-addition products of photochemically formed diphenylphosphinous acid (3) with acetone or phenanthrene quinone (8) are isolated in 59percent yields.Moreover, in neighboring-group participations aroyl radicals formed by competing α-cleavages of 1g-i yield 5- and 6-membered hetero- and carbocycles: xanthone (6), 3,3'-dimethoxy 3,3'-diphthalidyl (7), or the phenanthrene derivative 9, respectively.