817622-26-7

Basic information

• Product Name: (R)-2-(5-bromo-2-methoxyphenoxy)-1-phenylethanol
• Synonyms: (R)-2-(5-bromo-2-methoxyphenoxy)-1-phenylethanol
• CAS NO: 817622-26-7
• Molecular Weight: 323.186
• Mol File: 817622-26-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-2-(5-bromo-2-methoxyphenoxy)-1-phenylethanol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(5-bromo-2-methoxyphenoxy)-1-phenylethanol(817622-26-7)
• EPA Substance Registry System: (R)-2-(5-bromo-2-methoxyphenoxy)-1-phenylethanol(817622-26-7)

Safety Data

• Hazardous Substances Data: 817622-26-7(Hazardous Substances Data)

Upstream product

• 37942-01-1 5-bromo-2-methoxyphenol 
• 56751-12-3 2-chloro-1-phenylethanol 
• 25016-01-7 5-bromo-2-methoxybenzaldehyde 

Downstream Products

• 817622-41-6 (2R,5R)-9-bromo-6,6-dimethoxy-2-phenyl-1,4-dioxaspiro[4.5]deca-7,9-diene 

Relevant articles and documents

First asymmetric synthesis of orthoquinone monoketal enantiomers via anodic oxidation

(Chemical equation presented) An asymmetric synthesis of orthoquinone monoketals was accomplished using anodic oxidation to convert aryl methyl ethers bearing a chiral ethanol unit into orthoquinone bisketals, followed by monohydrolysis of their dimethyl ketal unit. All four possible stereoisomers were generated in a diastereoselective manner by varying the attachment point of the chiral pro-ketal alcoholic auxiliary to the starting arene. A preliminary screening of subsequent nucleophilic addition reactions confirmed the potential utility of these synthons in asymmetric synthesis.