82363-99-3Relevant articles and documents
Bimetallic Nanoshells as Platforms for Metallo- and Biometallo-Catalytic Applications
Kisukuri, Camila M.,Palmeira, Dayvson J.,Rodrigues, Thenner S.,Camargo, Pedro H.C.,Andrade, Leandro H.
, p. 171 - 179 (2016/01/25)
The use of gold, silver, platinum and palladium for preparation of bimetallic nanoshells (AgAu, AgPt, and AgPdNSs, respectively) and their use for metallo- and bio-metallo catalytic applications have been described. Bimetallic nanoshells (metallo-catalysts) were employed for silane oxidation to silanols and hydrogen (H2) production. Fast and efficient oxidation of several silanes was observed after only 1 h at room temperature, by employing AgPd NSs as catalyst, acetone as solvent, and water as oxidant. Interestingly, bio-metallo-catalysts (NSs-CALB) prepared from lipase attachment to the bimetallic nanoshells, displayed promising bi-catalytic activities (enzymatic: transesterification; metallic: silane oxidation).
Sila Perfumes, I. Sila Analogues of Tertiary Carbinols as Perfumes
Wrobel, Dieter,Tacke, Reinhold,Wannagat, Ulrich,Harder, Ulrich
, p. 1694 - 1704 (2007/10/02)
Silanols RR'R''SiOH 7 which are analog to carbinols 1 with strong odour in the region of flowery notes (lily of the valley-hyacinth-rose) were prepared via reaction steps (3) and partially unknown intermediates 6.Sila perfumes 7 are similar in intensity and spectrum of odour to 1 but a shift from lily of the valley towards hyacinth notes is generally observed.
