824-88-4

Basic information

• Product Name: O-phenyl thiocarbamate
• CAS NO: 824-88-4
• Molecular Formula: C₇H₇NOS
• Molecular Weight: 153.2016
• Mol File: 824-88-4.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 244.9°C at 760 mmHg
• Flash Point: 101.9°C
• Density: 1.254g/cm³
• Vapor Pressure: 0.0296mmHg at 25°C
• Refractive Index: 1.635
• CAS DataBase Reference: O-phenyl thiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: O-phenyl thiocarbamate(824-88-4)
• EPA Substance Registry System: O-phenyl thiocarbamate(824-88-4)

Safety Data

• Hazardous Substances Data: 824-88-4(Hazardous Substances Data)

Upstream product

• 1005-56-7 phenylcarbonochloridothioate 
• 16890-86-1 thiocarbamoyl chloride 
• 108-95-2 phenol 
• 1122-85-6 phenyl cyanate 
• 17356-08-0 thiourea 
• 4486-44-6 O,O-diisopropyl S-hydrogen phosphorothioate 
• 107-56-2 O,O-diisopropyl hydrogen phosphorodithioate 
• 333-20-0 potassium thioacyanate 

Downstream Products

• 13559-72-3 2-Phenoxy-thiazolin-dion-(4,5) 
• 622-52-6 p-methylphenylthiourea 
• 1135-19-9 N-Propionyl-thiocarbamidsaeure-O-phenylester 
• 88976-03-8 (2-Chloro-1-ethoxy-ethyl)-thiocarbamic acid O-phenyl ester 
• 33201-75-1 (2,2-Diphenyl-vinyl)-thiocarbamic acid O-phenyl ester 
• 33201-76-2 Fluoren-9-ylidenemethyl-thiocarbamic acid O-phenyl ester 
• 108-95-2 phenol 
• 73120-22-6 2-phenoxythiazole 
• 76510-77-5 4-Ethoxy-2-phenoxy-4,5-dihydro-thiazole 
• 13163-34-3 thiocarbonisocyanatidic acid O-phenyl ester 
• 13163-49-0 N--N'-phenyl-harnstoff 
• 13332-87-1 6-phenoxy-2,3-diphenyl-2,3-dihydro-[1,3,5]thiadiazin-4-one 
• 13163-39-8 2,4-dioxo-6-phenoxy-4H-[1,3,5]thiadiazine-3-carbothioic acid O-phenyl ester 
• 1352031-51-6 5-phenoxy-1,2,4-dithiazole-3-one 

Relevant articles and documents

Green and efficient synthesis of thioureas, ureas, primary: O -thiocarbamates, and carbamates in deep eutectic solvent/catalyst systems using thiourea and urea

An efficient and general catalysis process was developed for the direct preparation of various primary O-thiocarbamates/carbamates as well as monosubstituted thioureas/ureas by using thiourea/urea as biocompatible thiocarbonyl (carbonyl) sources. This procedure used choline chloride/tin(ii) chloride [ChCl][SnCl2]2 with a dual role as a green catalyst and reaction medium to afford the desired products in moderate to excellent yields. Moreover, the DES can be easily recovered and reused for seven cycles with no significant loss in its activity. Besides, the method shows very good performance for synthesizing the desired products on a large scale.

Synthesis and structure of substituted 5-phenoxy-1,2,4-dithiazole-3-ones

Seven new substituted 5-phenoxy-1,2,4-dithiazole-3-ones were prepared in modest yield (53-76%) from corresponding O-phenyl thiocarbamates and chlorocarbonylsulfenyl chloride in dry ether at-10 °C. All of the compounds were characterized by NMR and elemental analysis and some of them by X-ray diffraction. Preliminary kinetic measurements showed that the parent 5-phenoxy-1,2,4-dithiazole-3-one is a very efficient sulfurizing agent toward triphenyl phosphite. Copyright

REACTIONS OF ACID PHOSPHORO-THIOIC AND -DITHIOIC ESTERS WITH PHENYL CYANATE

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