82461-31-2

Basic information

• Product Name: 1,5-Dimethyl-6-oxa-bicyclo[3.1.0]hexane
• Synonyms: 1,5-Dimethyl-6-oxa-bicyclo[3.1.0]hexane
• CAS NO: 82461-31-2
• Molecular Formula: C₇H₁₂O
• Molecular Weight: 112.17
• Mol File: 82461-31-2.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,5-Dimethyl-6-oxa-bicyclo[3.1.0]hexane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Dimethyl-6-oxa-bicyclo[3.1.0]hexane(82461-31-2)
• EPA Substance Registry System: 1,5-Dimethyl-6-oxa-bicyclo[3.1.0]hexane(82461-31-2)

Safety Data

• Hazardous Substances Data: 82461-31-2(Hazardous Substances Data)

Usage

Structure

Bicyclic with a six-membered ring and an oxygen-containing bridge

Usage

Primarily used in research and chemical synthesis

Reactivity

Interesting for studying the reactivity and properties of bicyclic compounds

Hazards

Potential hazards have not been extensively studied or documented

Handling

Should be handled with caution

Applications

Potential applications in pharmaceuticals and materials science

Further exploration

An area of interest for further exploration and study

Upstream product

• 93-59-4 Perbenzoic acid 
• 765-47-9 1,2-dimethylcyclopentene 
• 136132-07-5 3-(bromomethyl)-3-phenyl-1,2-dioxetane 
• 1192-18-3 cis-1,2-dimethylcyclopentane 

Downstream Products

• 13505-34-5 2,6-heptandione 

Relevant articles and documents

Efficient and selective oxidation of methyl substituted cycloalkanes by heterogeneous methyltrioxorhenium-hydrogen peroxide systems

Polymer-supported methyltrioxorhenium (MTO) systems are efficient catalysts for the oxidative functionalisation of cyclohexane and cyclopentane derivatives with H2O2 as oxygen donor. Using poly(4-vinyl)pyridine and poly(4-vinyl)pyridine-N-oxide as MTO supports, cycloalkanol, cycloalkanediol, cycloalkanone and ω-hydroxy methyl ketone derivatives were obtained in different yields depending on the experimental conditions. Interestingly, cycloalkane dimers were selectively recovered in acceptable to good yields when the oxidation was performed with polystyrene-microencapsulated MTO catalyst. The EPR investigation suggests that the homolytic cleavage of the CH3-Re bond with formation of CH3{radical dot} radicals occurs inside the polystyrene capsule, indicating a possible role of methyl radical in the cycloalkane dimerisation pathway.

Neuartige Reaktionen von disubstituierten 1,2-Dioxetanen mit Olefinen al ?-Nucleophile: Cycloadditionen ueber 1,6-Dipole

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