82466-12-4

Basic information

• Product Name: Benzenemethanol, 2-bromo-, acetate
• CAS NO: 82466-12-4
• Molecular Formula: C9H9BrO2
• Molecular Weight: 229.073
• Mol File: 82466-12-4.mol
• Article Data: 28

Chemical Properties

• CAS DataBase Reference: Benzenemethanol, 2-bromo-, acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 2-bromo-, acetate(82466-12-4)
• EPA Substance Registry System: Benzenemethanol, 2-bromo-, acetate(82466-12-4)

Safety Data

• Hazardous Substances Data: 82466-12-4(Hazardous Substances Data)

Usage

Derivative of

Benzenemethanol (Benzyl alcohol)

Position of Bromine Atom

2-carbon position

Esterification

Further esterified with acetic acid

Common Uses

Organic synthesis
Reagent in various chemical reactions
Solvent in industrial processes
Flavoring agent in food products

Potential Applications

Pharmaceuticals
Fine chemicals

Versatile Reactivity

Due to functional groups

Upstream product

• 18982-54-2 o-bromobenzyl alcohol 
• 75-36-5 acetyl chloride 
• 95-46-5 2-methylphenyl bromide 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 64-19-7 acetic acid 
• 6630-33-7 ortho-bromobenzaldehyde 
• 141-78-6 ethyl acetate 
• 108-24-7 acetic anhydride 
• 94236-21-2 1-bromo-2-((methoxymethoxy)methyl)benzene 
• 392717-83-8 1-(benzyloxy)-4-((methoxymethoxy)methyl) benzene 
• 836-43-1 4-benzyloxybenzyl alcohol 
• 850335-71-6 2-bromo-1-[(ethoxymethoxy)methyl]benzene 
• 127-09-3 sodium acetate 
• 3433-80-5 1-Bromo-2-bromomethyl-benzene 

Downstream Products

• 6279-07-8 2-methyl-9H-xanthene 
• 304669-40-7 (2-(3,4-dihydro-2H-pyran-6-yl)phenyl)methanol 
• 1202867-79-5 (+)-(1S,3'S,4'R,6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydro-3H-spiro[isobenzofuran-1,2'-pyran]-3'-ol 
• 1177259-20-9 (+)-(1R,3'R,4'S,6'R)-6'-(2-(tert-butyldiphenylsilyloxy)ethyl)-4'-(triisopropylsilyloxy)-3',4',5',6'-tetrahydro-3H-spiro[isobenzofuran-1,2'-pyran]-3'-ol 

Relevant articles and documents

Bu 4 NI-Catalyzed C-C Bond Cleavage and Oxidative Esteri??cation of Allyl Alcohols with Toluene Derivatives

A novel oxidative esterification of 1-arylprop-2-en-1-ols with toluene derivatives catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alcohol and toluene derivatives. In addition, this protocol represents a new transformation of allyl alcohol involving C-C bond cleavage and C-O bond forming.

Selective acetylation of primary alcohols by ethyl acetate

A KOtBu and ethyl acetate mediated efficient methodology has been developed for the acetylation of primary and secondary alcohols where ethyl acetate is the source of acetyl group. The reaction is fast, mild, efficient, and highly selective towards the primary alcohols.

Preparation, characterization and application of RHA/TiO2 nanocomposites in the acetylation of alcohols, phenols and amines

In this work, anatase-phase nano-titania was prepared by embedding in rice husk ash, and identified using a variety of techniques. The obtained nanocomposite (RHA/TiO2) was used as a green and inexpensive catalyst for the promotion of the acetylation of alcohols, phenols and amines with Ac2O at room temperature under solvent free conditions. The procedure gave the products in excellent yields during all reaction times. Also this catalyst can be reused for several times without loss of its catalytic activity.