826-74-4Relevant articles and documents
Tertiary arsine ligands for the Stille coupling reaction
Chishiro, Akane,Imoto, Hiroaki,Inaba, Ryoto,Konishi, Masafumi,Naka, Kensuke,Yumura, Takashi
, p. 95 - 103 (2021/12/27)
The Stille coupling reaction is one of the most important coupling reactions. It is well known that the triphenylarsine ligand can accelerate the reaction rate of Stille coupling. However, other arsine ligands have never been investigated for the Stille c
Method for preparing olefin compound under alkaline condition
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Paragraph 0021-0023, (2021/05/29)
The invention relates to a method for preparing an olefin compound under an alkaline condition. The method comprises the following steps: adding a solvent and an alkali catalyst into long-chain alcohol serving as a raw material, introducing sulfuryl fluoride gas, stirring for reaction, and separating and purifying to obtain the olefin compound. The olefin compound has a structural formula shown in the description; and in the formula, R is phenyl, substituted phenyl, heterocyclic aryl, fused ring aryl, substituted fused ring aryl or alkyl. An alkali-promoted alcohol-to-olefin conversion method developed by the invention is mild in reaction condition, simple and convenient to operate and low in instrument and equipment requirements, the long-chain alcohol is used as a reaction raw material, the price is low, the source is wide, and the yield of the prepared olefin compound is high; and the method effectively avoids the influence of acidic conditions on part of groups (acetal, ketal, epoxy and the like), is efficient in reaction and wide in substrate application range, can tolerate most of functional groups, and provides a new path for synthesis of complex olefins.
Nickel-Catalyzed Reductive Cross-Coupling of Aryl Bromides with Vinyl Acetate in Dimethyl Isosorbide as a Sustainable Solvent
Huang, Xia,Jin, Jian,Lei, Chuanhu,Su, Mincong
supporting information, (2022/01/15)
A nickel-catalyzed reductive cross-coupling has been achieved using (hetero)aryl bromides and vinyl acetate as the coupling partners. This mild, applicable method provides a reliable access to a variety of vinyl arenes, heteroarenes, and benzoheterocycles, which should expand the chemical space of precursors to fine chemicals and polymers. Importantly, a sustainable solvent, dimethyl isosorbide, is used, making this protocol more attractive from the point of view of green chemistry.