83173-74-4Relevant articles and documents
Cp2TiCl2-Catalyzed Photoredox Allylation of Aldehydes with Visible Light
Bergamini, Giacomo,Calogero, Francesco,Cozzi, Pier Giorgio,Fermi, Andrea,Gualandi, Andrea,Guazzi, Simone,Mazzarini, Martino
, p. 3857 - 3863 (2020/03/26)
A Barbier-type Cp2TiCl2-mediated (10 mol %) photoredox allylation of aldehydes under irradiation with visible light (blue light-emitting diodes (LEDs), 450 nm) and in the presence of an organic dye (3DPAFIPN, 5 mol %) with allylbromides is described.
Direct, Mild, and General n-Bu4NBr-Catalyzed Aldehyde Allylsilylation with Allyl Chlorides
Tekle-Smith, Makeda A.,Williamson, Kevin S.,Hughes, Isaac F.,Leighton, James L.
supporting information, p. 6024 - 6027 (2017/11/10)
A direct, mild, and general method for the enantioselective allylsilylation of aldehydes with allyl chlorides is reported. The reactions are effectively catalyzed by 5 mol % of n-Bu4NBr, and this rate acceleration allows the use of complex allyl donors in fragment-coupling reactions and of electron-deficient allyl donors. The results are (1) significant progress toward a "universal" asymmetric aldehyde allylation reaction that can reliably and highly stereoselectively couple any allyl chloride-aldehyde combination and (2) the discovery of a novel mode of nucleophilic catalysis for aldehyde allylsilylation reactions.
Syn -Selective crotylation of aldehydes using bismuth-crotyl bromide-(1-butyl-3-methylimidazolium bromide) combination: Some synthetic applications
Goswami, Dibakar,Koli, Mrunesh R.,Chatterjee, Sucheta,Chattopadhyay, Subrata,Sharma, Anubha
, p. 3756 - 3774 (2017/07/07)
The Bi-[bmim][Br] combination has been found to offer high syn-selectivity in the crotylation of aldehydes with crotyl bromide using practically stoichiometric amounts of the reagents. The room temperature ionic liquid (RTIL), [bmim][Br], activated Bi metal in the presence of oxygen to produce crotylbismuthdibromide, which reacted with the aldehydes at room temperature. The major anti-syn diastereomeric product obtained from the crotylation of (R)-cyclohexylideneglyceraldehyde was utilized for the synthesis of dictyostatin and cryptophycin segments, and (+)-cis-aerangis lactone, using standard synthetic protocols.