83766-52-3Relevant articles and documents
Highly Site-Selective Formation of Perfluoroalkylated Anilids via a Protecting Strategy by Molybdenum Hexacarbonyl Catalyst
Yuan, Chunchen,Dai, Ping,Bao, Xiaoguang,Zhao, Yingsheng
supporting information, p. 6481 - 6484 (2019/08/20)
Introducing a perfluoroalkyl group on the aromatic ring with high site selectivity remains a challenging area in organofluorine chemistry. We herein report a highly para-selective C-H perfluoroalkylation of aniline substrates using the molybdenum hexacarbonyl catalyst. Various substituted anilids derived from anilids were well-tolerated, affording the corresponding products in moderate to good yields. Preliminary mechanism studies and density functional theory calculations revealed the coordination of Mo catalyst with amides as the key factor to realize para selectivity.
Facile fabrication of multifunctional perfluoroalkyl functionalized graphene hydrogel via a synchronous reduction and grafting strategy
Li, Ting,Ding, Yunqiao,Liu, Libin,Liu, Jian,Fang, Wenyuan,Xiang, Yu,Li, Tianduo
, p. 21744 - 21753 (2015/11/10)
Fluorine-containing groups represent very promising functionalities because fluorine not only changes the physico-chemical properties of the graphene surface, it may also alter its electronic and magnetic properties. Herein, we describe, for the first tim
Benign Perfluoroalkylation of Aniline Derivatives through Photoredox Organocatalysis under Visible-Light Irradiation
Barata-Vallejo, Sebastián,Yerien, Damian E.,Postigo, Al
supporting information, p. 7869 - 7875 (2015/12/24)
In this work, we present a room- or solar-light-initiated transition-metal-free radical homolytic aromatic substitution (HAS) reaction of aniline derivatives with perfluoroalkyl moieties employing perfluoroalkyl halides as readily available perfluoroalkyl