838-34-6

Basic information

• Product Name: Benzoxazole, 2-(4-methoxyphenyl)-
• CAS NO: 838-34-6
• Molecular Formula: C14H11NO2
• Molecular Weight: 225.247
• Mol File: 838-34-6.mol
• Article Data: 228

Chemical Properties

• CAS DataBase Reference: Benzoxazole, 2-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoxazole, 2-(4-methoxyphenyl)-(838-34-6)
• EPA Substance Registry System: Benzoxazole, 2-(4-methoxyphenyl)-(838-34-6)

Safety Data

• Hazardous Substances Data: 838-34-6(Hazardous Substances Data)

Upstream product

• 3117-67-7 (E)-N-(4-methoxybenzylidene)-2-hydroxyaniline 
• 114331-87-2 N-(2-hydroxy-phenyl)-4-methoxy-benzamide 
• 100-09-4 4-methoxybenzoic acid 
• 95-55-6 2-amino-phenol 
• 349614-89-7 N-(2-bromophenyl)-4-methoxybenzamide 
• 329939-01-7 N-(2-iodophenyl)-4-methoxybenzamide 
• 273-53-0 benzoxazole 
• 66107-29-7 4-methoxyphenyl triflate 
• 1180511-33-4 C₁₄H₁₂⁽²⁾HNO₂ 
• 7465-88-5 4-methoxy-N-phenylbenzamide 
• 3899-91-0 4-methoxyphenyl p-toluenesulfonate 
• 64908-64-1 2-phenoxyisoindol-1,3-dione 
• 4846-21-3 O-phenylhydroxylamine 
• 6462-50-6 sodium 4-methoxybenzenesulfinate 

Downstream Products

• 3315-19-3 2-(4-hydroxyphenyl)benzoxazole 
• 1573171-23-9 C₂₀H₂₂BNO₄ 
• 1444302-88-8 2-(2-fluoro-4-methoxyphenyl)benzo[d]oxazole 

Relevant articles and documents

Synthesis, Characterization and DFT-D Studies of 2-Aminoethoxycalix[4]resorcinarenes: A Novel Heterogeneous Organocatalyst

The present article reports the synthesis of two novel supramolecular architectures, Phenyl(octa-2-aminoethoxy)calix[4]resorcinarene and 2-Aminoethoxyphenyl-(octa-2-aminoethoxy)calix[4]resorcinarene via surface functionalization and describes their applic

Pd/Cu-Catalyzed C-H/C-H Cross Coupling of (Hetero)Arenes with Azoles through Arylsulfonium Intermediates

A highly efficient method for the selective formal C-H/C-H cross-coupling of azoles and (hetero)arenes was established through arylsulfonium intermediates under transition-metal catalysis, which produced a variety of 2-(hetero)aryl azoles in good to excellent yields. Advantages of the reaction included mildness, a good functional group tolerance, a wide range of substrates, a high regio- and chemoselectivity, one-pot procedures, and the late-stage functionalization of complex molecules without the use of oxidants, offering a promising strategy for the transition-metal-catalyzed C-H arylation of azoles.

Heterocyclic reaction inducted by Br?nsted–Lewis dual acidic Hf-MOF under microwave irradiation

Use of green chemistry and alternative strategies has been explored to prepare diverse organic derivatives. The combination between heterogeneous catalyst, environmentally benign reaction and high-yielding methods is gaining momentum. Herein, a defective 6-connected Hf-MOF, named Hf-BTC, was efficiently synthesized and characterized for the heterogeneous catalysis under microwave irradiation. The MOF features including structural defect, porosity, acidity, and stability was analyzed by powder X-ray diffraction, N2 sorption isotherms, acid-base titration, and thermal gravimetric analysis. In the catalytic studies, the Br?nsted-Lewis dual acidic Hf-BTC was efficiently applied for the synthesis of the heterocyclic compounds via the microwave-assisted cycloaddition and condensation reactions. The reactions proceeded smoothly in the presence of the Hf-MOF with a broad scope of substrates provided the expected products in high to excellent yields (up to 99 %) for few minutes and the catalyst could be easily recycle over many consecutive reactions without loss of its reactivity and structure.