84319-82-4Relevant articles and documents
REACTION OF SYN HEAD-TO-HEAD COUMARIN DIMER WITH AMINES AND THERMAL BEHAVIOR OF THE ADDUCTS
Hasegawa, Masaki,Katsuki, Hirokazu,Yonezawa, Noriyuki,Yoshida, Tsuyoshi,Ikebe, Yutaka
, p. 1325 - 1328 (2007/10/02)
The lacton-opening reaction of syn head-to-head coumarin dimer with amines gave c-3,c-4-bis(2-hydroxyphenyl)-r-1,c-2-cyclobutanedicarboxamides and/or -dicarboximides.The product ratio of the amide to the imide varied with the reaction temperature and the amount of amine used.Thermal reaction of these lactone-opened derivatives proceeded in two ways depending on the nature of amine moiety to give either the original coumarin dimer or 2,2'-dihydroxystilbene and the maleimide derivative.