845307-47-3

Basic information

• Product Name: DIMETHYL 3,3'-[2,2'-BIPYRIDINE]-4,4'-DIYLBIS-(2E,2'E)-2-PROPENATE
• Synonyms: DIMETHYL 3,3'-[2,2'-BIPYRIDINE]-4,4'-DIYLBIS-(2E,2'E)-2-PROPENATE
• CAS NO: 845307-47-3
• Molecular Formula: C18H16N2O4
• Molecular Weight: 0
• Mol File: 845307-47-3.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: DIMETHYL 3,3'-[2,2'-BIPYRIDINE]-4,4'-DIYLBIS-(2E,2'E)-2-PROPENATE(CAS DataBase Reference)
• NIST Chemistry Reference: DIMETHYL 3,3'-[2,2'-BIPYRIDINE]-4,4'-DIYLBIS-(2E,2'E)-2-PROPENATE(845307-47-3)
• EPA Substance Registry System: DIMETHYL 3,3'-[2,2'-BIPYRIDINE]-4,4'-DIYLBIS-(2E,2'E)-2-PROPENATE(845307-47-3)

Safety Data

• Hazardous Substances Data: 845307-47-3(Hazardous Substances Data)

Upstream product

• 1134-35-6 4,4'-dimethyl-2,2'-bipyridines 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 99970-84-0 [2,2']bipyridinyl-4,4'-dicarbaldehyde 

Downstream Products

• 845307-48-4 4,4′-bis(E-carboxyvinyl)-2,2′-bipyridine 

Relevant articles and documents

Synthesis and photophysical properties of new ruthenium(II) charge-transfer sensitizers containing a 4,7-bis(E-carboxyvinyl)-1,10-phenanthroline ligand

A series of ruthenium(II) complexes containing carboxyvinyl-conjugated phenanthroline and another auxiliary ligand have been designed, synthesized, and characterized. Starting from [RuCl2(p-cymene)]2, two types of Ru(II) complexes, [Ru(dcvphen)(4,7-R2-phenanthroline)(NCS) 2] and [Ru(dcvphen)(4,4′-R2-bipyridine)(NCS) 2] (dcvphen = 4,7-bis(E-carboxyvinyl)-1,10-phenanthroline, R = -CH = CHCOOH, -COOH, H), were synthesized by a one-pot reaction in DMF. Final products were obtained as a tetrabutylammonium salt form of Ru(II) complexes with reasonable yields. UV-Vis absorption studies on the newly synthesized Ru(II) complexes were carried out. Furthermore, it was shown that a dye-sensitized solar cell fabricated with representative [Ru(dcvphen)2(NCS) 2][TBA]2 complex dye exhibited a reasonable power conversion efficiency of 1.0 %.