849193-27-7

Basic information

• Product Name: chloro(N,N-diisopropylcarbamato)tris(triphenylphosphine)ruthenium
• Synonyms: chloro(N,N-diisopropylcarbamato)tris(triphenylphosphine)ruthenium
• CAS NO: 849193-27-7
• Molecular Weight: 1067.59
• Mol File: 849193-27-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: chloro(N,N-diisopropylcarbamato)tris(triphenylphosphine)ruthenium(CAS DataBase Reference)
• NIST Chemistry Reference: chloro(N,N-diisopropylcarbamato)tris(triphenylphosphine)ruthenium(849193-27-7)
• EPA Substance Registry System: chloro(N,N-diisopropylcarbamato)tris(triphenylphosphine)ruthenium(849193-27-7)

Safety Data

• Hazardous Substances Data: 849193-27-7(Hazardous Substances Data)

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 124-38-9 carbon dioxide 
• 108-18-9 diisopropylamine 
• 603-35-0 triphenylphosphine 

Downstream Products

• 114595-94-7 RuH₂(H₂)(PPh₃)3 
• 55102-19-7 hydridochlorotris(triphenylphosphine)ruthenium(II) 

Relevant articles and documents

New N,N-diisopropylcarbamato complexes of ruthenium(II) as catalytic precursors for olefin hydrogenation

During the synthesis of [Ru(O2CNiPr2) 2(PPh3)2] (1), the [RuCl2(PPh 3)3]/NHiPr2XCO2 system produces the intermediates [NH2iPr2][Ru2Cl 2(H-Cl)3(PPh3)4] (2) and [RuCl(O2C-NiPr2)(PPh3)3] (3) which have been isolated and fully characterised. Compound 2 contains the dinuclear anionic triply chloride-bridged rathenium(II) species. Compound 3 is mononuclear, the octahedral ruthenium centre being coordinated to the bidentate carbamato ligand. The reactions of compounds 1 and 3 with dihydrogen have been studied at room temperature and atmospheric pressure with respect to their catalytic hydrogenation of 1-octene. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.