84920-35-4

Basic information

• Product Name: 3-methyl-1-phenylhexa-4,5-dien-3-ol
• Synonyms: 3-methyl-1-phenylhexa-4,5-dien-3-ol
• CAS NO: 84920-35-4
• Molecular Weight: 188.269
• Mol File: 84920-35-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 3-methyl-1-phenylhexa-4,5-dien-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-1-phenylhexa-4,5-dien-3-ol(84920-35-4)
• EPA Substance Registry System: 3-methyl-1-phenylhexa-4,5-dien-3-ol(84920-35-4)

Safety Data

• Hazardous Substances Data: 84920-35-4(Hazardous Substances Data)

Upstream product

• 627-09-8 Propargyl acetate 
• 2550-26-7 4-Phenyl-2-butanone 
• 106-96-7 propargyl bromide 
• 57186-58-0 2-allenyl-5,5-dimethyl-1,3,2-dioxaborinane 
• 865350-17-0 4,4,5,5-tetramethyl-2-(propa-1,2-dien-1-yl)-1,3,2-dioxaborolane 
• 108521-65-9 prop-2-yn-1-yl 4-methylbenzoate 

Relevant articles and documents

Zinc Amide Catalyzed Regioselective Allenylation and Propargylation of Ketones with Allenyl Boronate

Zinc amide catalyzed, regioselective allenylation and propargylation of ketones with allenyl boronate is reported. Tertiary allenyl and homopropargyl alcohols were obtained, respectively, in high selectivities, from the same starting materials, simply by changing the reaction conditions. The substrate scope was wide. Mechanistic studies suggest that the reactions are controlled under kinetic and thermodynamic conditions.

Zinc-catalyzed allenylations of aldehydes and ketones

The general zinc-catalyzed allenylation of aldehydes and ketones with an allenyl boronate is presented. Preliminary mechanistic studies support a kinetically controlled process wherein, after a site-selective B/Zn exchange to generate a propargyl zinc int

Regioselective addition reactions of propargyl bromides to carbonyl compounds with gallium catalyzed by indium

Reactions of organogallium reagents generated from propargyl bromides having substituents at the γ-position and gallium in the presence of 5 mol % of indium with aldehydes and ketones selectively produced homoallenyl alcohols in good to excellent yields.