851363-60-5Relevant articles and documents
Higherature monoclinic α-SrHfF6, and isostructural α-SrZrF6: Associating Hf2F12 bipolyhedra and SrF8 snub disphenoids.
Laval, Jean-Paul,Mayet, Richard
, p. 229 - 235 (2018/02/14)
The structure of the higherature monoclinic variety α-SrHfF6 (strontium hafnium hexafluoride) [and of isostructural α-SrZrF6 (strontium zirconium hexafluoride)] associates Hf2F12 bipolyhedra and SrF8 snub disphenoids, forming zigzag twisted [SrF6]n layers. The distribution of the Hf and Sr polyhedra forms a three-dimensional framework which can be related to the family of anion-excess ReO3-related superstructures. α-SrHfF6 corresponds to a new ABX6 type and is compared to the other main families already described. A partial amorphization of this structure is observed in samples quenched from the melt.The crystal structure of α-SrHfF6 corresponds to a new structure type in the ABX6 series. It associates Hf2F12 bipolyhedra and SrF8 snub disphenoids, forming zigzag twisted [SrF6]n layers.
The reactions of silver, zirconium, and hafnium fluorides with liquid ammonia: Syntheses and crystal structures of Ag(NH3) 2F·2NH3, [M(NH3)4F 4]·NH3 (M = Zr, Hf), and (N2
Kraus, Florian,Baer, Sebastian A.,Fichtl, Matthias B.
, p. 441 - 447 (2009/04/13)
By reaction of the tetrafluorides MF4 or the ternary silver fluorides Ag3M2F14 (M = Zr, Hf) with dry liquid ammonia at -40°C, the pentaammoniates [M(NH3)4F 4]·NH3 (1,
Thermal stability and X-ray-luminescent properties of fluorozirconates and fluorosulfatozirconates
Godneva,Boroznovskaya,Motov,Klimkin,Mikhailova
, p. 563 - 567 (2009/06/19)
The thermolysis of fluorozirconates (M2ZrF6, M 5Zr4F21 ? 3H2O, MZrF 5 ? H2O, Rb2Zr3OF12, and Cs2Zr3F14/sub