85157-85-3

Basic information

• Product Name: (Z)-1-chloro-1-(4-methoxyphenyl)-1-propene
• Synonyms: (Z)-1-chloro-1-(4-methoxyphenyl)-1-propene
• CAS NO: 85157-85-3
• Molecular Weight: 182.65
• Mol File: 85157-85-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (Z)-1-chloro-1-(4-methoxyphenyl)-1-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-chloro-1-(4-methoxyphenyl)-1-propene(85157-85-3)
• EPA Substance Registry System: (Z)-1-chloro-1-(4-methoxyphenyl)-1-propene(85157-85-3)

Safety Data

• Hazardous Substances Data: 85157-85-3(Hazardous Substances Data)

Upstream product

• 79-37-8 oxalyl dichloride 
• 121-97-1 4-Methoxypropiophenone 
• 79-03-8 propionyl chloride 
• 98-86-2 acetophenone 
• 4180-23-8 E-1-(4'-methoxyphenyl)prop-1-ene 
• 2749-94-2 1-methoxy-4-(prop-1-yn-1-yl)benzene 
• 103505-40-4 4-(1,2-dichloro-propyl)-anisole 
• 64-17-5 ethanol 
• 141-52-6 sodium ethanolate 

Downstream Products

• 81112-07-4 2-chloro-1-(4'-methoxyphenyl)-propan-1-one 

Relevant articles and documents

Iodine(III)-Mediated Oxidative Hydrolysis of Haloalkenes: Access to α-Halo Ketones by a Release-and-Catch Mechanism

An unprecedented iodine(III)-mediated oxidative transposition of vinyl halides has been accomplished. The products obtained, α-halo ketones, are useful and polyvalent synthetic precursors. There are only a handful of reported examples of the direct conversion of vinyl halides to their corresponding α-halo carbonyl compounds. Insights into the mechanism and demonstration that this synthetic transformation can be done under enantioselective conditions are reported.

AN EFFICIENT METHOD FOR THE SYNTHESIS OF 1-ARYLALKYNES

1-Arylalkynes are prepared from propiophenones in good yield via the sequence a) 2 equiv PCl5/Δ b) DBN or Δ and c) Mg metal.