85287-85-0

Basic information

• Product Name: 3-Methyl-4-phenylsulfanyl-1-oxa-spiro[4.5]decan-2-one
• Synonyms: 3-Methyl-4-phenylsulfanyl-1-oxa-spiro[4.5]decan-2-one
• CAS NO: 85287-85-0
• Molecular Weight: 276.4
• Mol File: 85287-85-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Methyl-4-phenylsulfanyl-1-oxa-spiro[4.5]decan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Methyl-4-phenylsulfanyl-1-oxa-spiro[4.5]decan-2-one(85287-85-0)
• EPA Substance Registry System: 3-Methyl-4-phenylsulfanyl-1-oxa-spiro[4.5]decan-2-one(85287-85-0)

Safety Data

• Hazardous Substances Data: 85287-85-0(Hazardous Substances Data)

Upstream product

• 53282-55-6 (trimethylsiloxymethylidene)cyclohexane 
• 31469-22-4 1,1-bis(trimethylsilyloxy)prop-1-ene 
• 85287-83-8 [1-(Chloro-phenylsulfanyl-methyl)-cyclohexyloxy]-trimethyl-silane 
• 101704-19-2 1-((phenylthio)methyl)cyclohexanol 
• 85287-99-6 Trimethyl-(1-phenylsulfanylmethyl-cyclohexyloxy)-silane 
• 13307-75-0 (phenylthio)methyllithium 
• 108-94-1 cyclohexanone 
• 104750-38-1 (2RS,3SR)-2,6-dimethylphenyl 3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propionate 
• 133030-82-7 (2S,3R)-3-Hydroxy-2-methyl-3-(1-phenylsulfanyl-cyclohexyl)-propionic acid 
• 104750-47-2 (2R,3R)-3-Hydroxy-2-methyl-3-(1-phenylsulfanyl-cyclohexyl)-propionic acid methyl ester 
• 2043-61-0 cyclohexanecarbaldehyde 
• 57768-35-1 1-(phenylthio)-1-cyclohexanecarboxaldehyde 
• 133030-82-7 (2RS,3RS)-3-hydroxy-2-methyl-3-<1-(phenylthio)cyclohexyl>propionic acid 

Relevant articles and documents

Transformation of Cyclic α-Phenylthio Aldehydes by Stereoselective Aldol Reactions and Phenylthio Migration into Spirocyclic Lactones and Ethers, and E-Allylic Alcohols with 1,4-Related Chiral Centres

syn- and anti-Selective aldol reactions between enolates of propionate esters and three α-phenylthio cycloalkanecarbaldehydes give single diastereoisomers of phenylthio alcohols which rearrange in acid with 5-hydroxy or 5-CO2H participation to give spiroc

O-SILYLATED ENOLATE PHENYLTHIOALKYLATION: a SYNTHESIS OF α,β-UNSATURATED 5- AND 6-MEMBERED LACTONES.

ZnBr2-catalysed phenylthioalkylation of keten bis(trimethylsilyl)acetals, obtained from carboxylic acids, with appropriate α-chlorosulphides can be used to prepare γ- and δ-lactones.