85356-78-1

Basic information

• Product Name: 3-methylenepent-4-en-1-yl benzoate
• Synonyms: 3-methylenepent-4-en-1-yl benzoate
• CAS NO: 85356-78-1
• Molecular Weight: 202.253
• Mol File: 85356-78-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-methylenepent-4-en-1-yl benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methylenepent-4-en-1-yl benzoate(85356-78-1)
• EPA Substance Registry System: 3-methylenepent-4-en-1-yl benzoate(85356-78-1)

Safety Data

• Hazardous Substances Data: 85356-78-1(Hazardous Substances Data)

Upstream product

• 593-60-2 Vinyl bromide 
• 39252-69-2 2-iodoethyl benzoate 
• 32657-89-9 1,3-butadien-2-ylmagnesium chloride 

Relevant articles and documents

Nickel-catalyzed reductive 1,3-diene formation from the cross-coupling of vinyl bromides

Facile construction of 1,3-dienes building upon cross-electrophile coupling of two open-chain vinyl halides is disclosed in this work, showing moderate chemoselectivities between the terminal bromoalkenes and internal vinyl bromides. The present method is mild and tolerates a range of functional groups and can be applied to the total synthesis of a tobacco fragrance solanone.