859979-85-4

Basic information

• Product Name: 4-bromo-2-methoxy-5-nitro-phenol
• Synonyms: 4-bromo-2-methoxy-5-nitro-phenol
• CAS NO: 859979-85-4
• Molecular Weight: 248.033
• Mol File: 859979-85-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-bromo-2-methoxy-5-nitro-phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-bromo-2-methoxy-5-nitro-phenol(859979-85-4)
• EPA Substance Registry System: 4-bromo-2-methoxy-5-nitro-phenol(859979-85-4)

Safety Data

• Hazardous Substances Data: 859979-85-4(Hazardous Substances Data)

Upstream product

• 90-05-1 2-methoxy-phenol 
• 952008-39-8 1-acetoxy-4,5-dibromo-2-methoxy-benzene 
• 38926-86-2 1,2-dibromo-4-hydroxy-5-methoxybenzene 
• 75437-91-1 5-Bromo-4-nitro-2-phenoxymethoxy-phenol 
• 7748-58-5 1-bromo-4,5-methylenedioxy-2-nitrobenzene 
• 75437-98-8 1-Bromo-5-methoxy-2-nitro-4-phenoxymethoxy-benzene 
• 124-41-4 sodium methylate 
• 859979-83-2 1-acetoxy-4-bromo-2-methoxy-5-nitro-benzene 

Downstream Products

• 51072-66-3 1-bromo-4,5-dimethoxy-2-nitro-benzene 

Relevant articles and documents

Cleavage of Methylenedioxy Ring. II. Cleavage with Sodium Phenoxide and Methoxide in Dimethyl Sulfoxide

Regioselective cleavage of the methylenedioxy ring in piperonals (1, 6, and 7) and 3,4-methylenedioxynitrobenzenes (8 and 9) by oxide ions in dimethyl sulfoxide was achieved: the 4-hydroxybenzene derivatives (2, 10-13, and 22) were obtained with the phenoxide ion, while the 3-hydroxybenzene derivatives (4, 18-21, 23, 26, and 29) were obtained with the methoxide or benzyloxide ion.Keywords - cleavage of methylenedioxy ring; regioselectivity; piperonals; 3,4-methylenedioxynitrobenzenes; sodium phenoxide; sodium methoxide; dimethyl sulfoxide; 3-hydroxybenzene derivatives; 4-hydroxybenzene derivatives; NMR spectra